{"id":"W3200947711","doi":"10.1107/s2056989021009221","title":"X-ray crystal structure of [<i>L</i> <sub>2</sub>Ag<sub>3</sub>]<sup>+</sup>[OTf]<sup>−</sup>·5C<sub>6</sub>D<sub>6</sub>: a monoanionic bisphosphinimine ligand supported trisilver complex","year":2021,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Crystallographic Communications","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; University of Lethbridge","keywords":"Chemistry; Trifluoromethanesulfonate; Benzene; Ligand (biochemistry); Molecule; Crystallography; Crystal structure; Solvent; Stereochemistry; Metal; Medicinal chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004879711,0.0001664992,0.0001724993,0.00009359504,0.0001986346,0.0003015898,0.0004317766,0.0003807781,0.003722739],"category_scores_gemma":[0.0001155857,0.0001431026,0.00006842313,0.0002263219,0.0001508085,0.0001767745,0.00008511105,0.0005962708,0.0005490549],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003650888,"about_ca_system_score_gemma":0.0003309743,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002830042,"about_ca_topic_score_gemma":0.003148542,"domain_scores_codex":[0.9999707,0.000002165765,0.000001704916,0.0000074199,0.00001199243,0.000006012349],"domain_scores_gemma":[0.9999555,0.000007719023,0.00001190231,0.0000034204,0.00001024479,0.00001109764],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004572377,0.00007176233,0.001161218,0.0003013319,0.00001540914,0.0003145181,0.0001361279,0.001192402,0.9774125,0.002159927,0.007679751,0.009097856],"study_design_scores_gemma":[0.0002011128,0.0004097872,0.01874275,0.00004293491,0.00005751339,0.0008862925,0.0003594549,0.01093314,0.8833515,0.0005767463,0.08438744,0.00005136784],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9637821,0.002179507,0.006117521,0.0005945822,0.000124414,0.00006056635,0.006600176,0.0007002685,0.01984084],"genre_scores_gemma":[0.9654747,0.001432497,0.009638003,0.0001363387,0.00001897592,0.00004981405,0.009054023,0.0001736037,0.01402203],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003722739,"threshold_uncertainty_score":0.01245373,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0158320564734236,"score_gpt":0.2250731468778749,"score_spread":0.2092410904044514,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}