{"id":"W3201093978","doi":"10.48336/9rnf-fe46","title":"Synthesis of polycyclic aromatic hydrocarbon containing cyclophanes: new and improved methodologies","year":2022,"lang":"en","type":"dissertation","venue":"Memorial University Research Repository (Memorial University)","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Cyclophane; Chemistry; Characterization (materials science); Polycyclic aromatic hydrocarbon; Reactivity (psychology); Combinatorial chemistry; Aromaticity; Organic chemistry; Nanotechnology; Molecule; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002369154,0.0003757582,0.0002830561,0.0003635573,0.0002491862,0.0003189897,0.0003015921,0.000367782,0.003012939],"category_scores_gemma":[0.000203182,0.0002860904,0.0002787925,0.000439809,0.0002200423,0.001092737,0.0004832231,0.0009837938,0.001001533],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003713929,"about_ca_system_score_gemma":0.0004234558,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002388929,"about_ca_topic_score_gemma":0.0007728213,"domain_scores_codex":[0.9998353,0.00002274262,0.00001523298,0.00004471837,0.00006044674,0.00002152337],"domain_scores_gemma":[0.9999527,0.00000786363,0.00001306017,0.000009373589,0.00001083873,0.000006174065],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008660187,0.0001281598,0.0002031371,0.003477527,0.0000424877,0.0004858481,0.000426578,0.001977805,0.8724632,0.02166354,0.002340751,0.09670427],"study_design_scores_gemma":[0.00004205816,0.001045775,0.0009463733,0.0003584947,0.00006266081,0.001128009,0.000134083,0.0027724,0.7477201,0.002829107,0.2428921,0.00006883781],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.4916224,0.1476924,0.2620127,0.002376168,0.001350052,0.001189135,0.001801763,0.001044876,0.0909104],"genre_scores_gemma":[0.6362246,0.1580781,0.1655529,0.0006908237,0.0003025743,0.0008838264,0.001369964,0.0002359334,0.03666124],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.003012939,"threshold_uncertainty_score":0.01007926,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04255446830660875,"score_gpt":0.2801860722288558,"score_spread":0.2376316039222471,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}