{"id":"W3201408582","doi":"10.33774/chemrxiv-2021-2270g","title":"Photoluminescence and Electrochemiluminescence of Thermally Activated Delayed Fluorescence (TADF) Emitters Containing Diphenylphosphine Chalcogenide-Substituted Carbazole Donors","year":2021,"lang":"en","type":"preprint","venue":"","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Engineering and Physical Sciences Research Council; Horizon 2020 Framework Programme; Interreg; Natural Sciences and Engineering Research Council of Canada; European Commission; Vlaamse regering; Fonds De La Recherche Scientifique - FNRS; Swansea University","keywords":"Electrochemiluminescence; Carbazole; Electroluminescence; Photochemistry; Photoluminescence; Materials science; Fluorescence; HOMO/LUMO; Quenching (fluorescence); Phosphorescence; Phosphor; Chemistry; Optoelectronics; Nanotechnology; Electrode; Physical chemistry; Molecule; Organic chemistry; Physics; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002655904,0.0002613697,0.0001455565,0.000173105,0.00006030571,0.0002502629,0.0002844496,0.0003387318,0.0005142289],"category_scores_gemma":[0.0003595613,0.0001215902,0.0001331234,0.0002204537,0.000226619,0.0002885437,0.0001743343,0.0003498666,0.0001415627],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003847817,"about_ca_system_score_gemma":0.0001331779,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005090032,"about_ca_topic_score_gemma":0.0005714851,"domain_scores_codex":[0.9998536,0.00003193323,0.000008268576,0.00003800709,0.00004151807,0.0000267312],"domain_scores_gemma":[0.9998661,0.00005044807,0.00003249512,0.00001287791,0.00002373237,0.00001427251],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002598935,0.000005408652,0.00005488184,0.0000160548,0.000002071677,0.00002218355,0.00001316039,0.0001017322,0.9992064,0.00006798856,0.00000604163,0.0004781887],"study_design_scores_gemma":[0.000002639477,0.00004857124,0.0003304372,0.000001088758,0.000002489164,0.00002581721,0.000004071411,0.0005806059,0.9988382,0.000008451629,0.0001559457,0.000001694868],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945471,0.0003900573,0.004307144,0.00002240956,0.000004756134,0.0000101731,0.00007797255,0.00002673468,0.000613682],"genre_scores_gemma":[0.992063,0.0004031984,0.006223906,0.00001603669,0.000003171687,0.00002053808,0.0001355202,0.0000198273,0.001114711],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005142289,"threshold_uncertainty_score":0.002791762,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009240902075606872,"score_gpt":0.2207646464822787,"score_spread":0.2115237444066718,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}