{"id":"W3201740094","doi":"10.25972/opus-21300","title":"Selective C-X and C-H Borylation by N-Heterocyclic Carbene Nickel(0) Complex","year":2020,"lang":"en","type":"article","venue":"Online Publication Service of Würzburg University (Würzburg University)","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Mount Allison University; China Scholarship Council","keywords":"Borylation; Chemistry; Photochemistry; IMes; Carbene; Catalysis; Rhodium; Biphenyl; Organic synthesis; Photocatalysis; Reductive elimination; Oxidative addition; Pincer movement; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001238762,0.0003223826,0.0004417201,0.0004343267,0.0002961459,0.00004719376,0.0006405984,0.000269545,0.0013317],"category_scores_gemma":[0.0001650275,0.0004485655,0.0001325324,0.002414488,0.0001720619,0.00101227,0.0003839728,0.0003111403,0.00002351646],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000372352,"about_ca_system_score_gemma":0.0002003172,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004872976,"about_ca_topic_score_gemma":0.000118634,"domain_scores_codex":[0.9979926,0.0001212841,0.0003564932,0.0007673083,0.0004483801,0.0003139573],"domain_scores_gemma":[0.9969091,0.0002207327,0.0005708221,0.0004627986,0.001399244,0.0004373189],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.001858967,0.001386867,0.02696652,0.001379013,0.001014801,0.00003267283,0.003366107,0.0009536932,0.8828064,0.02070705,0.05195987,0.007568013],"study_design_scores_gemma":[0.004496946,0.00008840587,0.008108845,0.00006240011,0.0004102789,0.00001174936,0.007325328,0.01673522,0.01563882,0.00008388476,0.9461411,0.0008969777],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8717287,0.0001772253,0.02692305,0.04573736,0.0001294577,0.0006724916,0.003286579,0.0009216542,0.05042351],"genre_scores_gemma":[0.95498,0.0004078607,0.00871603,0.002702855,0.0002964463,9.938427e-7,0.01214108,0.0001055888,0.02064911],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.8941813,"threshold_uncertainty_score":0.9997966,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02969691671189485,"score_gpt":0.2368799090139204,"score_spread":0.2071829923020255,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}