{"id":"W3202801627","doi":"10.33774/chemrxiv-2021-pg6k3","title":"Fast Reverse Intersystem Crossing Over 107 s-1 in Organic Emitters with Inverted Singlet-Triplet Gap via Intramolecular Through Space Charge Transfer","year":2021,"lang":"en","type":"preprint","venue":"","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Intersystem crossing; Intramolecular force; Singlet state; Photochemistry; Materials science; Acceptor; Chemical physics; Chemistry; Excited state; Physics; Atomic physics; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002406332,0.0002548997,0.0001782647,0.0001602045,0.00010557,0.0003348891,0.0002687305,0.0002545114,0.0008869692],"category_scores_gemma":[0.0001589533,0.0001130451,0.0001841552,0.0001692204,0.0002195752,0.0003856375,0.0002101188,0.0004488345,0.0002351733],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004439623,"about_ca_system_score_gemma":0.0002021765,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003427411,"about_ca_topic_score_gemma":0.0006470272,"domain_scores_codex":[0.9998988,0.00001277426,0.000007066442,0.0000279167,0.0000292097,0.0000243287],"domain_scores_gemma":[0.9999238,0.00001910318,0.00002661183,0.000007617787,0.0000145559,0.000008332613],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003068719,0.00001346055,0.0001077263,0.00005088166,0.000004136075,0.00003759199,0.00002182272,0.0002345609,0.9966414,0.00060675,0.00003579408,0.002215127],"study_design_scores_gemma":[0.000005351882,0.00009640874,0.0002439645,0.000002377653,0.000004885969,0.00003447747,0.000009243256,0.001044273,0.9975629,0.00005758834,0.0009347113,0.000003855585],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926656,0.0007152113,0.004657475,0.00004244372,0.00001105878,0.00001408323,0.00009771917,0.0000856871,0.001710733],"genre_scores_gemma":[0.9946985,0.0004013374,0.003740425,0.00001742057,0.00000336469,0.00001877658,0.00007680871,0.00001588338,0.001027506],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008869692,"threshold_uncertainty_score":0.003221214,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01494772399015178,"score_gpt":0.2327162905119701,"score_spread":0.2177685665218183,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}