{"id":"W3203159251","doi":"10.26434/chemrxiv.12798083.v1","title":"Online HPLC Analysis of Buchwald-Hartwig Aminations from Within an Inert Environment","year":2020,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; University of British Columbia","keywords":"Iodobenzene; Chemistry; Catalysis; Combinatorial chemistry; Computer science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001102116,0.0004301715,0.0008900051,0.0002170133,0.00007956695,0.00008055226,0.0006825714,0.000487488,0.002429587],"category_scores_gemma":[0.0002033806,0.0004884763,0.0005556915,0.0004029015,0.0002241798,0.00007302249,0.0006826564,0.0009548209,0.0000510239],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003603719,"about_ca_system_score_gemma":0.0001544405,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001458587,"about_ca_topic_score_gemma":0.0003111513,"domain_scores_codex":[0.9974109,0.000002423845,0.0008511589,0.001035977,0.0004790912,0.0002204695],"domain_scores_gemma":[0.9969585,0.0001546574,0.0006921173,0.001862669,0.000094091,0.0002379808],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002770594,0.001409014,0.006009044,0.0002059772,0.003825682,0.00001815463,0.001930898,0.01805496,0.9677749,0.00006813798,0.000211458,0.0004640247],"study_design_scores_gemma":[0.0004944844,0.00001492969,0.02980907,0.0001289745,0.006945115,0.000001694519,0.000665792,0.1148342,0.8445897,0.0008981655,0.000821934,0.0007959474],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964237,0.0001130705,0.0004793194,0.0004167109,0.0001432429,0.000110556,0.001793634,0.0001807728,0.0003390471],"genre_scores_gemma":[0.9761571,0.00005259708,0.001181563,0.00004424314,0.0003742844,0.0000560328,0.02128049,0.00007116413,0.0007825237],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1231853,"threshold_uncertainty_score":0.9997567,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03551007656180785,"score_gpt":0.2875060276342662,"score_spread":0.2519959510724583,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}