{"id":"W3204503278","doi":"10.1002/anie.202111977","title":"Desulfonative Suzuki–Miyaura Coupling of Sulfonyl Fluorides","year":2021,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"Natural Sciences and Engineering Research Council of Canada; Horizon 2020 Framework Programme; China Scholarship Council; Agence Nationale de la Recherche; Compute Canada","keywords":"Sulfonyl; Coupling (piping); Chemistry; Materials science; Organic chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001831213,0.0001900546,0.0002310261,0.00009572275,0.00005657882,0.00004325833,0.0002782281,0.0001687038,0.003133898],"category_scores_gemma":[0.0008445256,0.0002104726,0.0001692992,0.0001570926,0.0001094244,0.0002944457,0.00008733563,0.0002043537,0.00002002725],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002482309,"about_ca_system_score_gemma":0.0001188287,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003954543,"about_ca_topic_score_gemma":0.000009074074,"domain_scores_codex":[0.9984596,0.000003980203,0.000425385,0.0003553744,0.0005650278,0.0001905916],"domain_scores_gemma":[0.9981424,0.0004059058,0.0002645203,0.0002731501,0.0008522517,0.0000618143],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004768567,0.0001458812,0.0009559189,0.00006072767,0.0001170182,0.0000313209,0.0001100676,0.00001914212,0.9919253,0.00115953,0.004504292,0.0009230938],"study_design_scores_gemma":[0.0003727322,0.000009596062,0.0001739546,0.000255121,0.00003199261,0.00002403241,0.000301486,0.0001435823,0.9885615,0.002093107,0.007833632,0.0001992566],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9468195,0.000293319,0.002470747,0.0006739725,0.0006572139,0.00005886281,0.0004138227,0.0002577608,0.04835476],"genre_scores_gemma":[0.9950593,0.0001758815,0.001513676,0.0001044825,0.001104789,0.00005446581,0.001022618,0.00003319173,0.000931668],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04823969,"threshold_uncertainty_score":0.9977774,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02007287539945846,"score_gpt":0.2713547201840348,"score_spread":0.2512818447845763,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}