{"id":"W3207993721","doi":"10.26434/chemrxiv.14058269.v1","title":"Total Synthesis, Isolation, Surfactant Properties, and Biological Evaluation of Ananatosides and Related Macrodilactone-Containing Rhamnolipids","year":2021,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Glycosylation and Glycoproteins Research","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Chicoutimi; Institut National de la Recherche Scientifique","funders":"Fonds de recherche du Québec – Nature et technologies; Fonds de Recherche du Québec - Santé; Université de Sherbrooke; Natural Sciences and Engineering Research Council of Canada; Liverpool John Moores University; Centre National de la Recherche Scientifique; Ministère de l'Enseignement supérieur, de la Recherche et de l'Innovation","keywords":"Glycosylation; Stereochemistry; Glycolipid; Rhamnose; Moiety; Chemistry; Anomer; Pulmonary surfactant; Chemical structure; Biochemistry; Polysaccharide; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001650617,0.0006389222,0.0002172391,0.0003395966,0.0001910229,0.0002601532,0.0001625192,0.0002029481,0.0004256143],"category_scores_gemma":[0.0001665103,0.00008595883,0.0002997363,0.0003543117,0.0001440983,0.0002605342,0.0002471089,0.0003132217,0.0002666677],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002045865,"about_ca_system_score_gemma":0.0003216846,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006443215,"about_ca_topic_score_gemma":0.0008628684,"domain_scores_codex":[0.9998858,0.00002243806,0.00001616467,0.00002181543,0.00003464659,0.0000190168],"domain_scores_gemma":[0.9998915,0.00001738938,0.00003104711,0.00001182412,0.00002500107,0.00002327713],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000255217,0.00001227179,0.00005267492,0.00002631061,0.000003908333,0.00002291644,0.00001130178,0.00009229065,0.9985122,0.00003534997,0.000004447607,0.001200739],"study_design_scores_gemma":[0.000002525042,0.0001555403,0.0004248781,0.000003908215,0.00001296279,0.00004120175,0.00001073703,0.0001491068,0.9983486,0.00001416653,0.0008327703,0.000003542542],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9875191,0.00283717,0.006917528,0.00003923564,0.00001873559,0.00008081261,0.000652698,0.00004977443,0.001884898],"genre_scores_gemma":[0.9809513,0.0036501,0.01209684,0.00003778518,0.00001303525,0.00007877999,0.001052701,0.00003208601,0.002087442],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006443215,"threshold_uncertainty_score":0.001484454,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05767348457619341,"score_gpt":0.2905570567931245,"score_spread":0.2328835722169311,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}