{"id":"W3208022729","doi":"10.1016/j.tet.2021.132538","title":"Stereochemistry of Eʹ and Eʹʹ decarboxylative-dehydration reactions and the bent bond / antiperiplanar hypothesis orbital model","year":2021,"lang":"en","type":"article","venue":"Tetrahedron","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université Laval","funders":"","keywords":"Alkane stereochemistry; Chemistry; Bent molecular geometry; Dehydration; Double bond; Stereochemistry; Delocalized electron; Resonance (particle physics); Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001546922,0.0001447617,0.0002736666,0.00003866753,0.0001141816,0.00003730561,0.00008209762,0.0001047705,0.00008286825],"category_scores_gemma":[0.0002713927,0.0001120824,0.00008534892,0.0001747109,0.0002204736,0.00009155595,0.00005931137,0.0001178133,0.000001347101],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002903308,"about_ca_system_score_gemma":0.00004212097,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000552335,"about_ca_topic_score_gemma":0.00001514331,"domain_scores_codex":[0.9990615,0.00001926007,0.0002912114,0.0002803366,0.0002079146,0.0001397697],"domain_scores_gemma":[0.9990103,0.0003918145,0.0001462056,0.0003302317,0.00006238095,0.00005911109],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002478753,0.000351538,0.01003042,0.0005559054,0.0006291853,0.0000267761,0.002506618,0.0001138274,0.9245894,0.002792315,0.0004239006,0.05773225],"study_design_scores_gemma":[0.0009613904,0.000009509275,0.001763047,0.00006778653,0.0002763308,0.00006635627,0.003091061,0.0122806,0.9797662,0.001147213,0.0003422189,0.0002282527],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9593514,0.001927628,0.0002389556,0.0002689861,0.00001402769,0.0000390259,0.00005219932,0.00002328674,0.03808454],"genre_scores_gemma":[0.9976485,0.0003684187,0.0006931798,0.00001760529,0.00004130324,0.00001210301,0.00002318122,0.00001578405,0.001179866],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.057504,"threshold_uncertainty_score":0.4570586,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01387254205238722,"score_gpt":0.2125976005614296,"score_spread":0.1987250585090424,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}