{"id":"W3208513522","doi":"10.5281/zenodo.2542646","title":"NMR, HPLC and HRMS data - General Cyclopropane Assembly via Enantioselective Transfer of a Redox-Active Carbene to Aliphatic Olefins","year":2019,"lang":"en","type":"dataset","venue":"Zenodo (CERN European Organization for Nuclear Research)","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"AstraZeneca (Canada)","funders":"European Commission","keywords":"Cyclopropane; Carbene; Redox; Enantioselective synthesis; Chemistry; Transfer hydrogenation; High-performance liquid chromatography; Combinatorial chemistry; Organic chemistry; Catalysis; Ruthenium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0004248225,0.000517993,0.0006854313,0.0004597427,0.0007298927,0.0003947052,0.002285793,0.0003603997,0.008604273],"category_scores_gemma":[0.0005561215,0.0005467132,0.0000956579,0.00063845,0.000158171,0.0003625573,0.002429672,0.0008065462,0.002095745],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003914701,"about_ca_system_score_gemma":0.00003405465,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004712715,"about_ca_topic_score_gemma":0.00001476245,"domain_scores_codex":[0.9961693,0.0002700658,0.0006338715,0.001395741,0.0008895053,0.0006415137],"domain_scores_gemma":[0.9963402,0.00005628456,0.0002770998,0.002167416,0.0008042471,0.0003547947],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0003600547,0.0003157688,3.963182e-7,0.001232319,0.0003599076,0.00003804233,0.0006331131,0.00003604697,0.2822237,0.00006634093,0.6871489,0.02758548],"study_design_scores_gemma":[0.0008373556,0.0003448458,0.00002570078,0.0002036153,0.0002176103,0.0002615197,0.0003667282,0.0002135029,0.03598855,0.00001987648,0.9609555,0.000565205],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"dataset","genre_gemma":"dataset","genre_scores_codex":[0.01416067,0.0001312169,0.001165623,0.00009402628,0.0001531013,0.0009345468,0.9772927,0.0003027037,0.005765399],"genre_scores_gemma":[0.01130998,0.0005566283,0.0002937914,0.00006807838,0.0003083792,4.011781e-7,0.9850875,0.001648133,0.0007270874],"genre_candidate":"dataset","genre_consensus":"dataset","teacher_disagreement_score":0.2738066,"threshold_uncertainty_score":0.9996985,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03978996850901722,"score_gpt":0.2695499091447636,"score_spread":0.2297599406357464,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}