{"id":"W3208513522","doi":"10.5281/zenodo.2542646","title":"NMR, HPLC and HRMS data - General Cyclopropane Assembly via Enantioselective Transfer of a Redox-Active Carbene to Aliphatic Olefins","year":2019,"lang":"en","type":"dataset","venue":"Zenodo (CERN European Organization for Nuclear Research)","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"AstraZeneca (Canada)","funders":"European Commission","keywords":"Cyclopropane; Carbene; Redox; Enantioselective synthesis; Chemistry; Transfer hydrogenation; High-performance liquid chromatography; Combinatorial chemistry; Organic chemistry; Catalysis; Ruthenium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001182784,0.004080286,0.002310536,0.003080236,0.001100531,0.002871307,0.003385537,0.002810906,0.05822437],"category_scores_gemma":[0.003170174,0.000784682,0.001672452,0.004349486,0.0005851095,0.001310918,0.001395104,0.002749717,0.0908353],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001735113,"about_ca_system_score_gemma":0.002806641,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01023046,"about_ca_topic_score_gemma":0.01739972,"domain_scores_codex":[0.9989016,0.000132763,0.00009590211,0.000440517,0.0002781175,0.0001510488],"domain_scores_gemma":[0.9985799,0.0004483188,0.0001930852,0.0003749847,0.0002608482,0.0001428883],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0004931338,0.0001002342,0.001741059,0.00464554,0.0001760712,0.0001004099,0.00003261951,0.001626394,0.002948655,0.001164856,0.981374,0.005597093],"study_design_scores_gemma":[0.0005753721,0.00007355343,0.00361842,0.0004908725,0.0001262483,0.0001219092,0.00004062479,0.001123004,0.004456434,0.002512732,0.9868085,0.00005252267],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"dataset","genre_gemma":"dataset","genre_scores_codex":[0.0002880588,0.0002729656,0.0001025976,0.0000306075,0.00001794911,0.00001200597,0.9979267,0.0006618875,0.000687174],"genre_scores_gemma":[0.0006069156,0.0001704496,0.0003934597,0.00003878898,0.000003500105,0.00004489583,0.9982849,0.00009058073,0.000366553],"genre_candidate":"dataset","genre_consensus":"dataset","teacher_disagreement_score":0.05822437,"threshold_uncertainty_score":0.1947799,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03978996850901722,"score_gpt":0.2695499091447636,"score_spread":0.2297599406357464,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}