{"id":"W3209146647","doi":"10.1039/d1cp03823k","title":"Design and engineering of a dual-mode absorption/emission molecular switch for all-optical encryption","year":2021,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Toronto Metropolitan University","funders":"Natural Sciences and Engineering Research Council of Canada; Ryerson University","keywords":"Chromophore; Encryption; Photochemistry; Logic gate; Molecule; Absorption (acoustics); Supramolecular chemistry; Materials science; Molecular engineering; Optoelectronics; Computer science; Chemistry; Nanotechnology; Organic chemistry; Algorithm","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00008251648,0.0002507252,0.0003786622,0.000004569536,0.00003265883,0.00003349598,0.0001547602,0.0001494372,0.0000304222],"category_scores_gemma":[0.0001868941,0.0002561595,0.0001424543,0.0001084309,0.0001458477,0.0001088306,0.0001329323,0.0001968033,0.000004462558],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006759724,"about_ca_system_score_gemma":0.0000885966,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001341201,"about_ca_topic_score_gemma":3.262287e-9,"domain_scores_codex":[0.9985633,0.000009791619,0.0002722456,0.0005169441,0.0002882826,0.0003494466],"domain_scores_gemma":[0.9989967,0.0002269443,0.00009909916,0.0003115762,0.0001556301,0.0002100109],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005897247,0.0002640229,0.000001125731,0.0004571621,0.00001895322,0.000006215176,0.00008386792,0.0004237455,0.9981439,0.0002406351,0.00007318603,0.0002282186],"study_design_scores_gemma":[0.000491303,0.00001333633,0.000001830162,0.00008720534,0.00006017097,0.00001349073,0.00001479491,0.03445669,0.9593046,0.005268665,0.00001953116,0.000268407],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9348665,0.00004349064,0.06462187,0.00005881799,0.0000217846,0.0001455258,0.00003470879,0.00006262204,0.0001446382],"genre_scores_gemma":[0.9881864,0.000006860368,0.01127009,0.00002846809,0.0003075488,0.00006566309,0.00008008304,0.00003147466,0.00002345616],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05335177,"threshold_uncertainty_score":0.9999891,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01313001501907765,"score_gpt":0.2520577218227563,"score_spread":0.2389277068036786,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}