{"id":"W3209830649","doi":"10.1139/cjc-2021-0259","title":"Generation of ultrafast, transient, highly acidic pH spikes in the radiolysis of water at very high dose rates: relevance for FLASH radiotherapy","year":2021,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Radiation Therapy and Dosimetry","field":"Medicine","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Radiolysis; Chemistry; Irradiation; Hydronium; Oxygen; Linear energy transfer; Ion; Radiochemistry; Analytical Chemistry (journal); Aqueous solution; Physical chemistry; Chromatography; Nuclear physics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003610213,0.0001150841,0.0003756059,0.00009341309,0.00004817004,0.00001285788,0.0001326755,0.0001108709,0.0003053229],"category_scores_gemma":[0.0001248276,0.00008071871,0.0002038875,0.000204718,0.0001131622,0.00008253473,0.000001223965,0.0001572176,4.811403e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001915225,"about_ca_system_score_gemma":0.000720221,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001082162,"about_ca_topic_score_gemma":0.0003780397,"domain_scores_codex":[0.9989072,0.00004844966,0.0005413425,0.0001205876,0.0001873397,0.000195088],"domain_scores_gemma":[0.9990309,0.0001288569,0.0002156653,0.0002140676,0.0002312901,0.0001791951],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002284245,0.00004325112,0.002275108,0.0001639583,0.000098744,0.0000668994,0.001451582,0.0004293292,0.9921781,0.000006076067,0.002066474,0.0009920244],"study_design_scores_gemma":[0.002703027,0.0001064423,0.001643455,0.0001143569,0.00007276377,0.0002588569,0.000233456,0.0000826036,0.9863383,0.00002405688,0.008343872,0.00007881558],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915693,0.004938765,0.0002194358,0.00284845,0.000141711,0.0001079239,0.00004271328,0.000001587637,0.0001301071],"genre_scores_gemma":[0.9975806,0.0006316579,0.0003273984,0.0004564063,0.0003992396,0.000004428531,0.00005917545,0.00001552428,0.0005255257],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006277398,"threshold_uncertainty_score":0.3343071,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01806924894919346,"score_gpt":0.2495601373886281,"score_spread":0.2314908884394347,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}