{"id":"W3210419644","doi":"10.1021/acs.accounts.1c00556","title":"Precision Synthesis of Conjugated Polymers Using the Kumada Methodology","year":2021,"lang":"en","type":"article","venue":"Accounts of Chemical Research","topic":"Conducting polymers and applications","field":"Materials Science","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Polymerization; Monomer; Steric effects; Conjugated system; Polymer; Atom-transfer radical-polymerization; Polymer chemistry; Chemistry; Catalysis; Combinatorial chemistry; Materials science; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004224783,0.0005487093,0.0003728621,0.000751797,0.0004094902,0.000447454,0.0002948269,0.0004636185,0.001129361],"category_scores_gemma":[0.0003042328,0.0003732143,0.0003247469,0.0004717928,0.0005329331,0.0006509431,0.0007171684,0.001424538,0.001085637],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004055939,"about_ca_system_score_gemma":0.0005252701,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00023783,"about_ca_topic_score_gemma":0.0006260196,"domain_scores_codex":[0.9996871,0.00005310401,0.00002531281,0.0001075956,0.00008588852,0.00004099968],"domain_scores_gemma":[0.9998978,0.00003050464,0.00002378201,0.00002380325,0.00001471692,0.00000928582],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004233476,0.00006059671,0.0001903999,0.0005691327,0.00002540714,0.0002245118,0.0002338406,0.0009868821,0.897125,0.03160024,0.0009876983,0.06795391],"study_design_scores_gemma":[0.00002074042,0.0002516058,0.0003338272,0.00004950349,0.00001632377,0.0002924869,0.00002001488,0.002490432,0.9560687,0.002168829,0.03824967,0.00003780204],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.3195367,0.04819364,0.5857117,0.00104312,0.0006777731,0.0006209936,0.0004516726,0.001705852,0.04205858],"genre_scores_gemma":[0.66146,0.0220678,0.3032031,0.0004190154,0.0001060281,0.0006232123,0.0002737416,0.0002171606,0.01162989],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.001129361,"threshold_uncertainty_score":0.0037781,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.2564023541094677,"score_gpt":0.4607909211331008,"score_spread":0.2043885670236332,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}