{"id":"W3210696692","doi":"10.1002/hlca.202100209","title":"Advances in Stereoselective Iron(II)‐Catalyzed Synthesis of Sulfilimines with <i>N</i>‐Mesyloxycarbamates","year":2021,"lang":"en","type":"article","venue":"Helvetica Chimica Acta","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Canada Foundation for Innovation; Centre in Green Chemistry and Catalysis","keywords":"Chemistry; Stereoselectivity; Amination; Reagent; Ligand (biochemistry); Oxazoline; Catalysis; Selectivity; Pyridine; Chloride; Medicinal chemistry; Combinatorial chemistry; Organic chemistry; Stereochemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003565134,0.0004597036,0.000181754,0.000181263,0.0001008836,0.0002080697,0.0003665506,0.0002403831,0.0008784035],"category_scores_gemma":[0.0001592532,0.0001722848,0.0001732163,0.000102123,0.000200547,0.0002847,0.0002112082,0.0003353172,0.0003906847],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003381478,"about_ca_system_score_gemma":0.0002466398,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00041339,"about_ca_topic_score_gemma":0.0007686928,"domain_scores_codex":[0.999871,0.00003042804,0.00001317852,0.00002387833,0.00003357053,0.0000278258],"domain_scores_gemma":[0.9999224,0.000009749158,0.00002409403,0.00001219428,0.00001546106,0.00001608128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001019708,0.00003924201,0.0001537414,0.0001252754,0.000007261569,0.0001315406,0.00004775076,0.0002872791,0.9880922,0.001302016,0.0001153267,0.009596377],"study_design_scores_gemma":[0.00002981085,0.0002986758,0.0005375232,0.000005573425,0.00001069505,0.0002482477,0.00001222828,0.0009676152,0.99252,0.0001320783,0.00522897,0.000008663333],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9520228,0.006092884,0.02815468,0.0002701734,0.00006665771,0.0001001614,0.0002254739,0.0003565649,0.01271053],"genre_scores_gemma":[0.9849613,0.002507309,0.01012323,0.00003835693,0.00002156915,0.00003586949,0.0001292989,0.00002782315,0.002155228],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008784035,"threshold_uncertainty_score":0.002938509,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006787630140255618,"score_gpt":0.2207472848335591,"score_spread":0.2139596546933035,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}