{"id":"W3210733234","doi":"10.1039/d1dt03129e","title":"Heterobimetallic complexes stabilized by the P<sub>2</sub>N<sub>2</sub> macrocyclic ligand system: synthesis and reactivity of a rhodium–copper system that activates molecular hydrogen","year":2021,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Rhodium; Chemistry; Cyclooctene; Hydrogenolysis; Reactivity (psychology); Bimetallic strip; Copper; Ligand (biochemistry); Stereochemistry; Medicinal chemistry; Crystallography; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006400938,0.0002165259,0.0001476398,0.0001240297,0.0002154897,0.0003193838,0.0003010902,0.0002384685,0.001747422],"category_scores_gemma":[0.0001166014,0.0001383486,0.00005508996,0.00007432148,0.0001639058,0.0001569466,0.0002070491,0.0001741263,0.0004665276],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003138587,"about_ca_system_score_gemma":0.0001372721,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006620169,"about_ca_topic_score_gemma":0.001627049,"domain_scores_codex":[0.9999313,0.00001032525,0.000003260597,0.00001556395,0.00001717061,0.00002238851],"domain_scores_gemma":[0.9999553,0.000004469294,0.00001412749,0.000006027194,0.000005363766,0.00001465766],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002021153,0.00002872896,0.0001256599,0.00004713838,0.00001209256,0.00005351952,0.00003475382,0.0002639884,0.9958378,0.000782949,0.0004175758,0.002193625],"study_design_scores_gemma":[0.0000361848,0.0002211358,0.0009256148,0.000004025279,0.00001062298,0.0001043549,0.00002137391,0.001438427,0.9935572,0.0001049089,0.00356792,0.000008172344],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909034,0.0006545615,0.001902602,0.00005574134,0.00002071894,0.00002284668,0.00006649336,0.0001475031,0.006226161],"genre_scores_gemma":[0.9968619,0.0001411294,0.0009292407,0.00002149408,0.000004070391,0.00001359183,0.00007380763,0.00002096286,0.001933761],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001747422,"threshold_uncertainty_score":0.005845726,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0115609744763149,"score_gpt":0.2042906339525167,"score_spread":0.1927296594762018,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}