{"id":"W3211886061","doi":"10.1002/anie.202112770","title":"Deoxygenative Functionalizations of Aldehydes, Ketones and Carboxylic Acids","year":2021,"lang":"en","type":"review","venue":"Angewandte Chemie International Edition","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":97,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies; Canada Excellence Research Chairs, Government of Canada; Canada Foundation for Innovation","keywords":"Deoxygenation; Electrophile; Chemistry; Organic chemistry; Nucleophile; Carboxylic acid; Reactivity (psychology); Alkyl; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002650103,0.0004752916,0.001052176,0.0003282273,0.0001075468,0.00007869452,0.0003013331,0.0004900577,0.009443424],"category_scores_gemma":[0.0009687231,0.000487473,0.000468827,0.000465547,0.0002069064,0.0002664146,0.0002112385,0.0003646246,0.00002045235],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004133495,"about_ca_system_score_gemma":0.0004734739,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003134497,"about_ca_topic_score_gemma":0.00000825112,"domain_scores_codex":[0.9973125,0.00005911482,0.0009737551,0.0006784644,0.0007689545,0.0002072362],"domain_scores_gemma":[0.9970236,0.0007111569,0.0008199731,0.0003792499,0.0009438465,0.0001221412],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00009516183,0.001330113,0.0002436653,0.04075038,0.008967002,0.00009554614,0.0008054292,0.00008411347,0.007453826,0.03762222,0.08700826,0.8155443],"study_design_scores_gemma":[0.0003318048,0.000007891715,0.000007823975,0.004624364,0.0007212182,0.0001779942,0.00008506692,0.00002721689,0.02068566,0.0004227589,0.972495,0.0004131694],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.000006798823,0.965023,0.009888091,0.0001062866,0.001668357,0.0001717349,0.001794373,0.0000936643,0.02124769],"genre_scores_gemma":[0.00005941637,0.9673152,0.001175583,0.00005624885,0.002261741,0.0002367836,0.0234145,0.00008361469,0.005396917],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.8854868,"threshold_uncertainty_score":0.9997577,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05061828737006251,"score_gpt":0.3437632663765317,"score_spread":0.2931449790064691,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}