{"id":"W3212343872","doi":"10.1002/anie.202113947","title":"An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small‐Molecule Activation and Rearrangement Chemistry","year":2021,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"H2020 European Research Council; Studienstiftung des Deutschen Volkes; China Scholarship Council; Coordenação de Aperfeiçoamento de Pessoal de Nível Superior; National Natural Science Foundation of China; Natural Sciences and Engineering Research Council of Canada; European Commission; Alexander von Humboldt-Stiftung","keywords":"Chelation; Chemistry; Ligand (biochemistry); Small molecule; Molecule; Combinatorial chemistry; Stereochemistry; Medicinal chemistry; Receptor; Organic chemistry; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001053143,0.0002726273,0.0001333967,0.000160608,0.0001845087,0.0002002669,0.0003618739,0.0002367027,0.001793332],"category_scores_gemma":[0.00007880143,0.0001467213,0.0001076171,0.0001384722,0.0001991017,0.0002316714,0.0002374917,0.0003396811,0.000444106],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003728099,"about_ca_system_score_gemma":0.0002951656,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008950927,"about_ca_topic_score_gemma":0.002026084,"domain_scores_codex":[0.9999267,0.000009379524,0.000004044835,0.00001565912,0.00001392818,0.00003028845],"domain_scores_gemma":[0.9999648,0.000003697465,0.0000075191,0.000006347944,0.000006149465,0.00001135787],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008789357,0.00002016796,0.00005532487,0.00008784546,0.000004943289,0.00005921742,0.00003219589,0.0001500474,0.9953229,0.001316985,0.0001222517,0.002740169],"study_design_scores_gemma":[0.00002426949,0.0003274223,0.0003710844,0.000006524449,0.000009457468,0.0001334312,0.00001727987,0.0006090373,0.9914204,0.0001018948,0.006966671,0.00001265016],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9742858,0.001957024,0.01145721,0.0002288206,0.00009216138,0.0001374081,0.0003513402,0.00026166,0.01122845],"genre_scores_gemma":[0.99123,0.0004175933,0.005353973,0.00004668416,0.00000547283,0.00003603384,0.0001366067,0.00001425395,0.002759345],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001793332,"threshold_uncertainty_score":0.005999267,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01461280596094798,"score_gpt":0.2508616894133807,"score_spread":0.2362488834524327,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}