{"id":"W3213289083","doi":"10.22215/etd/2014-11697","title":"Part A: Enantioselective Synthesis of C9 and C10 Deuterio-Labelled Dihydrosterculic Acids Part B: Efficient, and Scalable Preparation of bis(Deuterium)- and 13C-Labeled Diazomethane.","year":2014,"lang":"en","type":"dissertation","venue":"","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"","keywords":"Chemistry; Enantioselective synthesis; Diazomethane; Cyclopentane; Nitroso; Sulfoxide; Swern oxidation; Toluene; Nitromethane; Methanol; Aldehyde; Deuterium; Organic chemistry; Wittig reaction; Medicinal chemistry; Stereochemistry; Dimethyl sulfoxide; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0006108989,0.0004131138,0.0009429169,0.0002340643,0.0001767724,0.00003432256,0.0001184463,0.00075105,0.0003318324],"category_scores_gemma":[0.0003568904,0.0003598585,0.00009738834,0.0002720931,0.0003060504,0.0001148254,0.00007579252,0.0004353569,0.000004019775],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003124169,"about_ca_system_score_gemma":0.0000807934,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006302995,"about_ca_topic_score_gemma":0.00008019122,"domain_scores_codex":[0.9978222,0.0003202615,0.0007281961,0.0006031441,0.0001828454,0.0003433129],"domain_scores_gemma":[0.9977005,0.001118575,0.000524955,0.0002209549,0.0002332251,0.0002018632],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002281953,0.0005870074,0.004589973,0.001525645,0.0007918325,0.000002577619,0.001187216,0.00001456071,0.9688592,0.0003999034,0.0006930056,0.01906711],"study_design_scores_gemma":[0.001696405,0.0003859946,0.002561131,0.0002416939,0.00101849,0.00001629187,0.0002964405,0.001905727,0.9591098,0.0000669376,0.03223024,0.0004707922],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899549,0.001428159,0.00002522677,0.00004353224,0.000476717,0.0007430231,0.0001124986,0.00003926009,0.007176661],"genre_scores_gemma":[0.9907315,0.005540527,0.0001416149,0.00006382482,0.00009285342,0.0001840299,0.0002002124,0.00003802022,0.003007407],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03153723,"threshold_uncertainty_score":0.9998853,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03709316158311383,"score_gpt":0.3826560928612148,"score_spread":0.3455629312781009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}