{"id":"W3213289083","doi":"10.22215/etd/2014-11697","title":"Part A: Enantioselective Synthesis of C9 and C10 Deuterio-Labelled Dihydrosterculic Acids Part B: Efficient, and Scalable Preparation of bis(Deuterium)- and 13C-Labeled Diazomethane.","year":2014,"lang":"en","type":"dissertation","venue":"","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"","keywords":"Chemistry; Enantioselective synthesis; Diazomethane; Cyclopentane; Nitroso; Sulfoxide; Swern oxidation; Toluene; Nitromethane; Methanol; Aldehyde; Deuterium; Organic chemistry; Wittig reaction; Medicinal chemistry; Stereochemistry; Dimethyl sulfoxide; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002574867,0.0006630408,0.000268149,0.0003571254,0.0002051639,0.0001975279,0.0003452606,0.0002884282,0.005098541],"category_scores_gemma":[0.0001862725,0.0002092561,0.0002446153,0.0002777279,0.0002387472,0.0002489029,0.0002808443,0.0004499556,0.002998911],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003544857,"about_ca_system_score_gemma":0.0006876768,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008407672,"about_ca_topic_score_gemma":0.001014819,"domain_scores_codex":[0.9998852,0.00001235974,0.0000104488,0.00003101883,0.00003165268,0.00002923762],"domain_scores_gemma":[0.9999235,0.00001316805,0.00001642395,0.00001798164,0.00001260184,0.00001632537],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009692693,0.00002724595,0.00005309972,0.00009070878,0.000004955368,0.00004717039,0.0000158229,0.0001886762,0.9914643,0.0004668048,0.0003211027,0.007223216],"study_design_scores_gemma":[0.00001337401,0.0001123904,0.0002324921,0.000003947224,0.000005704274,0.0001093854,0.000006215851,0.000184027,0.9939505,0.00005736097,0.005320111,0.000004425836],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7825476,0.007178878,0.1371758,0.0004260975,0.0003035599,0.001141718,0.007072837,0.001603069,0.0625506],"genre_scores_gemma":[0.8663434,0.008501021,0.08486068,0.0002950642,0.0000852029,0.0005673156,0.0075343,0.0003361477,0.03147667],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005098541,"threshold_uncertainty_score":0.01705635,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03709316158311383,"score_gpt":0.3826560928612148,"score_spread":0.3455629312781009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}