{"id":"W3216766097","doi":"10.1021/acs.joc.1c02352","title":"Reaction of Alkynyl- and Alkenyltrifluoroborates with Propargyldicobalt Cations: Alkynylation, Alkenylation, and Cyclopropanation Product Pathways","year":2021,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Chemistry; Cyclopropanation; Reactivity (psychology); Propargyl; Cyclopropane; Potassium; Lewis acids and bases; Medicinal chemistry; Stereochemistry; Natural product; Organic chemistry; Ring (chemistry); Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004260435,0.0001777353,0.0002723088,0.00003861555,0.0001672894,0.00004030146,0.000131815,0.00008857578,0.0001987455],"category_scores_gemma":[0.0005879573,0.000130998,0.00003735002,0.0003817268,0.0001877025,0.0003155495,0.00005164921,0.0003352241,0.000001054173],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000130279,"about_ca_system_score_gemma":0.0005547694,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002117785,"about_ca_topic_score_gemma":0.00001805788,"domain_scores_codex":[0.9986418,0.00002883865,0.0005959092,0.0001988179,0.0003904605,0.0001441901],"domain_scores_gemma":[0.9973167,0.0001779883,0.0009019177,0.0003710692,0.001139549,0.00009274628],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006166614,0.00009766619,0.002328179,0.0002123958,0.0001345413,0.000006389748,0.0005198424,0.00001876132,0.993872,0.00002602535,0.0001196455,0.002602894],"study_design_scores_gemma":[0.000687982,0.00002293836,0.004542675,0.0001617708,0.000325871,0.00336898,0.001736338,0.00007471231,0.9877079,0.0004170613,0.0008025419,0.0001512057],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936382,0.003265995,0.000499015,0.001291628,0.00003577761,0.0000787102,0.00001293547,0.00002351949,0.001154215],"genre_scores_gemma":[0.9973424,0.001318762,0.0006685599,0.00001307443,0.000219336,0.000003233178,0.00004172371,0.00002870754,0.0003641736],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006164068,"threshold_uncertainty_score":0.5341942,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008332992479964286,"score_gpt":0.2015610900587509,"score_spread":0.1932280975787866,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}