{"id":"W3217173605","doi":"10.26434/chemrxiv.13148234.v1","title":"Using Photoactive N-Heterocyclic Carbenes Monolayers to Identify the Influence of Surface Proximity on Photoswitching Activity","year":2020,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Ministry of Energy, Israel; Azrieli Foundation; Hebrew University of Jerusalem; European Commission","keywords":"Photoisomerization; Isomerization; Photochemistry; Monolayer; Chemistry; Azobenzene; Molecule; Adsorption; Photochromism; Metal; Materials science; Nanotechnology; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001320853,0.0004889686,0.0005578439,0.00002665432,0.0002224705,0.00009419362,0.00104624,0.0003959595,0.00005043823],"category_scores_gemma":[0.0002388244,0.0004436912,0.000299395,0.0002342601,0.0001215852,0.00009851095,0.0009661324,0.001403056,0.00001242988],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002640885,"about_ca_system_score_gemma":0.000128637,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005948076,"about_ca_topic_score_gemma":0.000008055697,"domain_scores_codex":[0.9978374,0.0000316465,0.0004251642,0.0009774505,0.0003898961,0.0003384119],"domain_scores_gemma":[0.9974164,0.0002840536,0.0005857727,0.001395081,0.0001267259,0.0001919574],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009417003,0.0001249255,0.0007534357,0.0006237883,0.0001401031,0.00000251758,0.0008886848,0.03199056,0.9652507,0.000006683739,0.00001993956,0.0001044381],"study_design_scores_gemma":[0.0001627248,0.000005975346,0.002161772,0.0004369962,0.0001111335,0.000002883403,0.0001747802,0.001770132,0.9942741,0.0004053829,0.0000912166,0.0004028454],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972383,0.00002492429,0.0001364433,0.0004587363,0.00005227385,0.0004728028,0.00007549977,0.0001178254,0.001423234],"genre_scores_gemma":[0.9992042,0.0000182137,0.0002468835,0.00011342,0.0001463265,0.000145552,0.00001971363,0.00005538533,0.00005028224],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03022043,"threshold_uncertainty_score":0.9998015,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06964252079754941,"score_gpt":0.3475798808135643,"score_spread":0.2779373600160149,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}