{"id":"W35792498","doi":"10.1021/acs.orglett.2c01634","title":"Synthesis of 1- and 1,2-Substituted Cyclopropylamines from Ketone Homoenolates.","year":2022,"lang":"en","type":"article","venue":"PubMed","topic":"Science, Research, and Medicine","field":"Medicine","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"University of Toronto; Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Canada Research Chairs; Alfred P. Sloan Foundation","keywords":"Climate change; Business; Political science; Environmental resource management; Environmental planning; Economics; Geography; Geology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001270412,0.0003994685,0.0001327417,0.0002223144,0.0001894322,0.0001399108,0.0002503275,0.0002428181,0.002841083],"category_scores_gemma":[0.0001512659,0.00013293,0.0001622914,0.0002258111,0.0001144471,0.0003932088,0.0002655633,0.00043179,0.0006519023],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001842529,"about_ca_system_score_gemma":0.000361437,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004484378,"about_ca_topic_score_gemma":0.001972735,"domain_scores_codex":[0.999921,0.00001319565,0.000007882745,0.00001576844,0.00001168597,0.00003052141],"domain_scores_gemma":[0.9999372,0.000007078828,0.00001779853,0.000009577288,0.0000122015,0.00001629556],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002229802,0.00007194105,0.0004419934,0.001058337,0.00003925257,0.0008524156,0.0002847501,0.0005534884,0.9677941,0.003283972,0.001135145,0.02426166],"study_design_scores_gemma":[0.00003328571,0.0006509181,0.001714977,0.00005486028,0.00003157917,0.0007878467,0.00008913385,0.0006237765,0.9703648,0.0003411806,0.02528096,0.00002661303],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9064611,0.01538458,0.0279595,0.0004767097,0.0003999952,0.0003592138,0.002436923,0.0003690878,0.04615286],"genre_scores_gemma":[0.9747138,0.005316515,0.01220426,0.0001137621,0.00002238271,0.0000904859,0.0005752146,0.00003009816,0.006933419],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002841083,"threshold_uncertainty_score":0.009504378,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0290623402119693,"score_gpt":0.2524889855870421,"score_spread":0.2234266453750728,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}