{"id":"W4200048105","doi":"10.26434/chemrxiv-2021-0c291","title":"NHCs and Visible Light-mediated Photoredox Co-catalyzed Radical 1,2-Dicarbonylation of Alkenes for 1,4-Diketones","year":2021,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Kootenay Association for Science & Technology","funders":"","keywords":"Ketyl; Radical; Chemistry; Photoredox catalysis; Photochemistry; Quenching (fluorescence); Photocatalysis; Selectivity; Catalysis; Combinatorial chemistry; Organic chemistry; Fluorescence","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000182582,0.000395252,0.0001467066,0.0001358723,0.0001180406,0.0001455872,0.0002219262,0.0003083595,0.001717175],"category_scores_gemma":[0.0001199097,0.0001248151,0.0002180942,0.0001269521,0.0001949583,0.0002913039,0.0003004333,0.0004640343,0.0004607144],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003307601,"about_ca_system_score_gemma":0.0002090973,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007473226,"about_ca_topic_score_gemma":0.001146044,"domain_scores_codex":[0.9998364,0.00001457667,0.000009594413,0.00005535867,0.00004178038,0.00004225514],"domain_scores_gemma":[0.9999499,0.000006929022,0.00001505277,0.00001071889,0.00000863987,0.000008826145],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004546529,0.00001856235,0.00005731604,0.00007135158,0.00000587325,0.00004831335,0.00002327208,0.0001085278,0.9964916,0.0005272457,0.0001350677,0.002467393],"study_design_scores_gemma":[0.000006110256,0.00005930568,0.0002242369,0.000001694098,0.00000396441,0.00004919264,0.000005660658,0.0002129992,0.9974654,0.00003864589,0.001929335,0.000003506282],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9740443,0.002901115,0.01164812,0.0002347447,0.000173347,0.0001177842,0.000348523,0.0002350463,0.01029697],"genre_scores_gemma":[0.9873604,0.0009607329,0.005003188,0.0000621523,0.00002298436,0.00004940401,0.0002348132,0.00003795285,0.006268348],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001717175,"threshold_uncertainty_score":0.005744517,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01704880875989164,"score_gpt":0.2767223618961248,"score_spread":0.2596735531362331,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}