{"id":"W4200232529","doi":"10.1002/ange.202116171","title":"Dearomative Cyclopropanation of Naphthols via Cyclopropene Ring‐Opening","year":2021,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Cégep de Saint-Laurent; University of Toronto","funders":"Kennarshore","keywords":"Cyclopropene; Cyclopropanation; Cyclopropane; Chemoselectivity; Chemistry; Ring (chemistry); Catalysis; Rhodium; Molecule; Combinatorial chemistry; Computational chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000137782,0.000250055,0.0003756461,0.00006549396,0.0001122211,0.00004209471,0.0002213453,0.000177986,0.002039222],"category_scores_gemma":[0.0001792715,0.0002577211,0.000155718,0.0003254819,0.00006099653,0.0002412539,0.0001700283,0.0002649505,0.00007293653],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001700336,"about_ca_system_score_gemma":0.0001254917,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006331232,"about_ca_topic_score_gemma":0.0000198683,"domain_scores_codex":[0.9983112,0.00002184509,0.0004436538,0.0004664398,0.000442069,0.0003147452],"domain_scores_gemma":[0.9985948,0.000076592,0.0003003433,0.0005120753,0.0004022828,0.0001138793],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002657997,0.0000712117,0.0004083832,0.0002827317,0.00007329255,0.00006300089,0.0006506871,0.00001074661,0.9920025,0.0001918313,0.00006660099,0.006152388],"study_design_scores_gemma":[0.000669213,0.00001476724,0.0002616065,0.000166139,0.00005987189,0.0001301711,0.001171844,0.00001993632,0.9914988,0.0005689921,0.005151308,0.0002873784],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8142543,0.0007508961,0.0007685017,0.00009765662,0.0001287257,0.0001035825,0.00002361005,0.0001570603,0.1837157],"genre_scores_gemma":[0.9916616,0.0001156217,0.004434247,0.00004528073,0.0001660269,0.00004274075,0.0001766694,0.00005663921,0.003301165],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1804145,"threshold_uncertainty_score":0.9999875,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01708664500260141,"score_gpt":0.24832224830446,"score_spread":0.2312356033018586,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}