{"id":"W4200235352","doi":"10.1039/d1dt04220c","title":"Pseudotetrahedral Zn(<scp>ii</scp>)-(<i>R</i> or <i>S</i>)-dihalogen-salicylaldiminato complexes with Λ- or Δ-chirality induction at-metal","year":2021,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Isfahan; York University; Alexander von Humboldt-Stiftung","keywords":"Diastereomer; Chemistry; Chirality (physics); Enantiopure drug; Crystallography; Metal; Stereochemistry; Intramolecular force; Molecule; Organic chemistry; Catalysis; Enantioselective synthesis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0000962065,0.0004659797,0.0004502934,0.000166969,0.001205885,0.0001057706,0.0002473104,0.0002876382,0.002853408],"category_scores_gemma":[0.0000674527,0.0003872591,0.0004309241,0.0009181356,0.0002811145,0.0003941952,0.00003503409,0.0007272189,0.00003183211],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001664276,"about_ca_system_score_gemma":0.0002852968,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003875023,"about_ca_topic_score_gemma":0.006142844,"domain_scores_codex":[0.9974884,0.00008140031,0.00053015,0.0008142114,0.0004613666,0.0006244608],"domain_scores_gemma":[0.9983147,0.0001966594,0.0001792599,0.0007630619,0.0002373028,0.0003089725],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003799295,0.001455802,0.0003247175,0.0002499574,0.0007621901,0.0004754753,0.001313476,0.0003891731,0.9904271,0.0003022818,0.001865863,0.002054004],"study_design_scores_gemma":[0.001273424,0.0002104973,0.0004379155,0.00007889968,0.0004348413,0.002631122,0.00265422,0.00005493205,0.732663,0.00007185808,0.2591916,0.0002976917],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9748404,0.0001880397,0.01179802,0.000487026,0.0006212885,0.0002051574,0.001211216,0.0004710516,0.01017778],"genre_scores_gemma":[0.971466,0.0001417216,0.001669244,0.0003324735,0.0001464473,0.0001571607,0.0006352138,0.00008478302,0.02536695],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2577642,"threshold_uncertainty_score":0.9998579,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02221052769153911,"score_gpt":0.2581513535221208,"score_spread":0.2359408258305817,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}