{"id":"W4200235352","doi":"10.1039/d1dt04220c","title":"Pseudotetrahedral Zn(<scp>ii</scp>)-(<i>R</i> or <i>S</i>)-dihalogen-salicylaldiminato complexes with Λ- or Δ-chirality induction at-metal","year":2021,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Isfahan; York University; Alexander von Humboldt-Stiftung","keywords":"Diastereomer; Chemistry; Chirality (physics); Enantiopure drug; Crystallography; Metal; Stereochemistry; Intramolecular force; Molecule; Organic chemistry; Catalysis; Enantioselective synthesis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005103942,0.0001977851,0.0001894024,0.00009721659,0.0001296816,0.0002995998,0.0004322881,0.0001242427,0.002475556],"category_scores_gemma":[0.0001186662,0.0001569867,0.00009776386,0.0001718056,0.0002305265,0.0001439267,0.0001877351,0.0002264942,0.0005351235],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002579134,"about_ca_system_score_gemma":0.0002549381,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006139176,"about_ca_topic_score_gemma":0.001184395,"domain_scores_codex":[0.9999503,0.000004568133,0.000003999754,0.00001338347,0.00001552881,0.00001221491],"domain_scores_gemma":[0.9999119,0.000009991657,0.00003016296,0.0000151207,0.00001040759,0.00002239072],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001839924,0.00001620348,0.0004657248,0.00008640328,0.00001134612,0.00008410573,0.00002666574,0.0003831306,0.9955947,0.0005803503,0.0002151659,0.002352139],"study_design_scores_gemma":[0.00007378973,0.0002678155,0.003196403,0.000004249092,0.00002190739,0.0004952751,0.00009752048,0.00364372,0.9868284,0.0003049281,0.005055344,0.00001067457],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903751,0.0001698709,0.005090286,0.00006997365,0.00003215261,0.0000338285,0.0002219375,0.0002019207,0.003805066],"genre_scores_gemma":[0.9950606,0.00007606261,0.002821726,0.0000209474,0.000003070686,0.00002065238,0.0002442034,0.00003292143,0.001719701],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002475556,"threshold_uncertainty_score":0.008281589,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02221052769153911,"score_gpt":0.2581513535221208,"score_spread":0.2359408258305817,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}