{"id":"W4200375396","doi":"10.1002/cmtd.202100068","title":"Pressurized Sample Infusion","year":2021,"lang":"en","type":"article","venue":"Chemistry - Methods","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Electrospray ionization; Simple (philosophy); Process engineering; Sample (material); Mass spectrometry; Computer science; Scale (ratio); Moisture; Ionization; Chemistry; Chromatography; Engineering; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002420802,0.000170609,0.0002363375,0.00001157038,0.0001169405,0.00005714271,0.0002754883,0.000203731,0.05846203],"category_scores_gemma":[0.0007145182,0.000180813,0.0001353839,0.0002772745,0.00004885049,0.00004292267,0.0002140283,0.0002838502,0.000009737425],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005596335,"about_ca_system_score_gemma":0.00007588707,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001293465,"about_ca_topic_score_gemma":3.200841e-7,"domain_scores_codex":[0.9989027,0.00003162471,0.0002256781,0.0004265874,0.0001544925,0.0002588757],"domain_scores_gemma":[0.9984235,0.0003744387,0.00009968536,0.0008547806,0.0001172008,0.0001303612],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00000494177,0.00007313152,0.0001676394,0.0001688398,0.00001982399,0.000005663153,0.00001691952,9.193948e-7,0.9772467,0.0007129212,0.001540459,0.02004203],"study_design_scores_gemma":[0.0001423223,0.000001145954,0.00001370649,0.00001621144,0.00001911185,0.00001953118,0.00002903421,0.0001802829,0.666184,0.00666266,0.3265936,0.0001383086],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"methods","genre_scores_codex":[0.06665191,0.001099429,0.1471592,0.000821259,0.00006346314,0.00008759952,0.0001404962,0.0009617318,0.7830149],"genre_scores_gemma":[0.04929658,0.0001668208,0.9248717,0.00009281376,0.0002831903,0.0001362549,0.0002796678,0.00004122687,0.02483175],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.7777125,"threshold_uncertainty_score":0.9423987,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02848953633036407,"score_gpt":0.3673500850631622,"score_spread":0.3388605487327982,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}