{"id":"W4200394285","doi":"10.3762/bjoc.17.196","title":"Iron-catalyzed domino coupling reactions of π-systems","year":2021,"lang":"en","type":"review","venue":"Beilstein Journal of Organic Chemistry","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Domino; Chemistry; Catalysis; Domino effect; Mindset; Organic synthesis; Coupling reaction; Atom economy; Noble metal; Nanotechnology; Biochemical engineering; Reactivity (psychology); Combinatorial chemistry; Organic chemistry; Computer science; Political science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00113442,0.0006585555,0.003286067,0.0001452015,0.00009965504,0.0001005688,0.0008687511,0.0008768964,0.01103227],"category_scores_gemma":[0.002083381,0.0006309699,0.001430269,0.000737462,0.0001405083,0.0001391116,0.0002199024,0.001311395,0.00002047663],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000788177,"about_ca_system_score_gemma":0.002831883,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000637434,"about_ca_topic_score_gemma":3.750685e-7,"domain_scores_codex":[0.9945362,0.0000619608,0.003565283,0.0005045247,0.0009769225,0.0003550858],"domain_scores_gemma":[0.991175,0.001089919,0.005336401,0.001104362,0.0009799633,0.0003143514],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00009595961,0.001257683,0.0000474128,0.3414006,0.006209889,0.0007415148,0.0002089744,0.0003929348,0.5140807,0.0001115825,0.006292118,0.1291607],"study_design_scores_gemma":[0.000830759,0.000007934028,1.794644e-7,0.02828535,0.002800121,0.006668597,0.0003308137,0.00002396513,0.02480213,0.000006570207,0.9356822,0.0005614039],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0003654067,0.9956442,0.001029183,0.00001534638,0.0008364705,0.0001085251,0.0001368738,0.0000333515,0.001830708],"genre_scores_gemma":[0.0001407274,0.9880977,0.0006959282,0.000002464909,0.001941222,0.00001300868,0.0004773559,0.0001807972,0.008450789],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9293901,"threshold_uncertainty_score":0.9996142,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04473947539916069,"score_gpt":0.3245853439539174,"score_spread":0.2798458685547567,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}