{"id":"W4200445395","doi":"10.1016/j.cattod.2021.12.008","title":"Morphological changes of vanadyl pyrophosphate due to thermal excursions","year":2021,"lang":"en","type":"article","venue":"Catalysis Today","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":13,"is_retracted":false,"has_abstract":false,"ca_institutions":"Polytechnique Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Catalysis; Butane; Chemistry; Calcination; Chemical engineering; Oxygen; Maleic anhydride; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001460689,0.0001278755,0.0003234421,0.0001097999,0.00009720962,0.0000145252,0.0001912731,0.00006383799,0.001402632],"category_scores_gemma":[0.0002004786,0.0001191754,0.0001902839,0.000797027,0.00003079884,0.0000429771,0.0001949508,0.0001447756,0.0001437461],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005633156,"about_ca_system_score_gemma":0.00003148495,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007387463,"about_ca_topic_score_gemma":0.00005230479,"domain_scores_codex":[0.9989666,0.00003225421,0.0002466901,0.0003004429,0.0002383454,0.0002157077],"domain_scores_gemma":[0.999036,0.0001056531,0.00007301894,0.0004880005,0.000141211,0.0001560815],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000103511,0.0001467648,0.0000936144,0.000009660269,0.0001095678,0.00008383819,0.0001996243,0.005939379,0.9871497,0.0004164151,0.001594238,0.004246839],"study_design_scores_gemma":[0.0001948804,0.00002052973,0.001942679,0.00001337632,0.0001461123,0.0000373875,0.0002920847,0.001118852,0.9746678,0.00002071708,0.02134623,0.0001992994],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915639,0.0003928241,0.003563878,0.002252799,0.0001769658,0.00008253239,0.0001094782,0.00007673714,0.001780904],"genre_scores_gemma":[0.9954983,0.00001251685,0.0004784191,0.0002714503,0.00008094425,0.00005175883,0.0003771468,0.00001776834,0.003211688],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01975199,"threshold_uncertainty_score":0.9995102,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01523482947483271,"score_gpt":0.2426564040606551,"score_spread":0.2274215745858224,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}