{"id":"W4200465073","doi":"10.26434/chemrxiv-2021-pgfm8","title":"Thermal Stability and Decomposition Pathways in VolatileMolybdenum(VI) Bis-Imides","year":2021,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"Natural Sciences and Engineering Research Council of Canada; University of Windsor; University of Ottawa","keywords":"Thermogravimetric analysis; Chemistry; Molybdenum; Thermal decomposition; Adduct; Thermal stability; Chemical vapor deposition; Alkyl; Differential scanning calorimetry; Decomposition; Volatility (finance); Atomic layer deposition; Inorganic chemistry; Physical chemistry; Organic chemistry; Layer (electronics)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001336159,0.0002127546,0.0001236129,0.0001343879,0.0001889992,0.0002247281,0.0002777144,0.0001776526,0.0006842212],"category_scores_gemma":[0.0001685743,0.0001417279,0.00009941366,0.000140493,0.0001692917,0.00019011,0.0001422375,0.0002974575,0.0001185137],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003001061,"about_ca_system_score_gemma":0.00009697937,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008856939,"about_ca_topic_score_gemma":0.001170851,"domain_scores_codex":[0.9999244,0.00001049734,0.000005713297,0.00002004565,0.00002173496,0.00001756513],"domain_scores_gemma":[0.9999381,0.00001289658,0.00002155671,0.00000619007,0.00001330148,0.000007800974],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008802287,0.000007954824,0.0005173889,0.00004367366,0.000006461185,0.00003707929,0.00005480988,0.0002118198,0.9977725,0.0001027713,0.00002768611,0.001129943],"study_design_scores_gemma":[0.00000492876,0.00008215877,0.002167702,0.000004472101,0.000006280601,0.00006971062,0.00002855314,0.0006161796,0.9963158,0.00001943877,0.0006812225,0.000003678576],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978478,0.0005713544,0.0007322921,0.00001649234,0.000002788678,0.000005809698,0.0001355845,0.00002247281,0.0006654706],"genre_scores_gemma":[0.9975554,0.0004208587,0.001032943,0.000009567315,0.000002176286,0.000009414407,0.0002362066,0.0000161837,0.000717356],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008856939,"threshold_uncertainty_score":0.002288997,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02745968624267659,"score_gpt":0.2398273303933221,"score_spread":0.2123676441506455,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}