{"id":"W4205169403","doi":"10.1002/chin.201016054","title":"ChemInform Abstract: Bismuth Triflate Catalyzed Addition of Allylsilanes to N‐Alkoxycarbonylamino Sulfones: Convenient Access to 3‐Cbz‐Protected Cyclohexenylamine.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Trifluoromethanesulfonate; Bismuth; Catalysis; Service (business); Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Business; Marketing","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002879254,0.000603825,0.000705851,0.000354931,0.0001727356,0.000249616,0.001149891,0.0005394705,0.004437458],"category_scores_gemma":[0.0009746113,0.0006229188,0.000291527,0.0008067472,0.0002105499,0.0006305948,0.000428116,0.000767269,0.0002992398],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002663764,"about_ca_system_score_gemma":0.0003601222,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006428941,"about_ca_topic_score_gemma":0.000293302,"domain_scores_codex":[0.9965189,1.776187e-8,0.001245306,0.0006779818,0.0007373274,0.0008204381],"domain_scores_gemma":[0.9965061,0.0002230914,0.0005962279,0.001484882,0.0005587132,0.0006310149],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002206748,0.000164619,0.0001174134,0.0004065026,0.0000774228,0.00001171282,0.001175946,0.000004892833,0.940659,0.00003360007,0.005714809,0.05141343],"study_design_scores_gemma":[0.001215539,0.00002727001,0.00353473,0.0001728078,0.00007578176,0.00007285974,0.0003168026,0.00003069715,0.9627659,0.00003278591,0.03106836,0.0006864647],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8671588,0.00001055261,0.000001231046,0.0002264279,0.0004221607,0.0006215114,0.0006373668,0.0003386543,0.1305832],"genre_scores_gemma":[0.9860169,0.000008491744,0.00004827426,0.000105362,0.0004312577,0.0004043657,0.001746197,0.00009006176,0.01114908],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1194342,"threshold_uncertainty_score":0.9996222,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01555456292304117,"score_gpt":0.2710087869502371,"score_spread":0.2554542240271959,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}