{"id":"W4205291540","doi":"10.1007/s12678-022-00708-8","title":"Novel Dithiolene Nickel Complex Catalysts for Electrochemical Hydrogen Evolution Reaction for Hydrogen Production in Nonaqueous and Aqueous Solutions","year":2022,"lang":"en","type":"article","venue":"Electrocatalysis","topic":"Metalloenzymes and iron-sulfur proteins","field":"Energy","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; National Research Council Canada","funders":"National Natural Science Foundation of China; National Science Foundation","keywords":"Catalysis; Chemistry; Nickel; Electrochemistry; Acetonitrile; Hydrogen production; Cyclic voltammetry; Pyridinium; Inorganic chemistry; Aqueous solution; Bulk electrolysis; Medicinal chemistry; Physical chemistry; Organic chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008444515,0.0002263029,0.0002556744,0.0001952382,0.0001187658,0.0003633867,0.000588337,0.0003072128,0.0008493282],"category_scores_gemma":[0.0001655378,0.0001570822,0.00009318822,0.000184775,0.000158828,0.0003174322,0.0002407443,0.0003009909,0.0003515718],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002958826,"about_ca_system_score_gemma":0.0001135936,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005104213,"about_ca_topic_score_gemma":0.001178274,"domain_scores_codex":[0.9998806,0.00001247813,0.000009150132,0.00002268616,0.00005871287,0.00001629917],"domain_scores_gemma":[0.9999635,0.000005767638,0.000007500325,0.000004308948,0.000009967884,0.000008931627],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006379289,0.00001636572,0.00009315926,0.00008115396,0.000006354354,0.00002664912,0.00001905402,0.00008148667,0.9969324,0.0003040131,0.00007009038,0.002305517],"study_design_scores_gemma":[0.000017344,0.0000583799,0.0002662164,0.000002937434,0.000007604926,0.00006449636,0.00001493423,0.001560875,0.9955679,0.0000368945,0.002397723,0.000004730416],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9758316,0.003241295,0.01545736,0.0002221456,0.00007061181,0.00006427157,0.0001929533,0.0003748937,0.004544775],"genre_scores_gemma":[0.9912451,0.0007104604,0.005970793,0.0000260171,0.000008499133,0.00002665804,0.0001300157,0.00001892936,0.001863569],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008493282,"threshold_uncertainty_score":0.002841294,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02122032613397257,"score_gpt":0.2366050089445478,"score_spread":0.2153846828105752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}