{"id":"W4205515617","doi":"10.1039/d1cc06439h","title":"9-BBN and chloride catalyzed reduction of chlorophosphines to phosphines and diphosphines","year":2022,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Council for the Arts; Deutsche Forschungsgemeinschaft; American Chemical Society; Royal Society of Chemistry; Canada Research Chairs","keywords":"Diphosphines; Chemistry; Catalysis; Alkyl; Chloride; Lewis acids and bases; Phenylsilane; Combinatorial chemistry; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002562399,0.0004583389,0.0002106301,0.0003006296,0.0001883341,0.0002881036,0.0005829211,0.0005071611,0.007032203],"category_scores_gemma":[0.0002854474,0.0002714999,0.0001264965,0.0002204186,0.0001906013,0.0004547579,0.0004572893,0.0006961699,0.003892091],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004717854,"about_ca_system_score_gemma":0.0003926256,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009693131,"about_ca_topic_score_gemma":0.002369554,"domain_scores_codex":[0.9996533,0.00004312406,0.00002684975,0.0001147261,0.00008911498,0.00007287551],"domain_scores_gemma":[0.9999025,0.00001659323,0.00002628084,0.00001209161,0.00002589119,0.0000167031],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009675776,0.00002033861,0.00005837251,0.0002473097,0.000005111358,0.0001175109,0.00003154434,0.00007504199,0.9945186,0.0005212238,0.0003647096,0.003943467],"study_design_scores_gemma":[0.000006333669,0.00005722039,0.0001498969,0.000007497484,0.00000359019,0.000176991,0.00001074613,0.0002146953,0.9912612,0.00005261711,0.008056044,0.000003185877],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8397822,0.004489657,0.07553828,0.0005381173,0.0004809472,0.0003579977,0.003112233,0.001194668,0.07450593],"genre_scores_gemma":[0.9494517,0.001656074,0.02280888,0.0001255929,0.00002978018,0.0001572596,0.002587446,0.0001648161,0.02301851],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007032203,"threshold_uncertainty_score":0.02352512,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01815141269494523,"score_gpt":0.2384716026840225,"score_spread":0.2203201899890773,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}