{"id":"W4205524401","doi":"10.1002/9781119951438.eibc0166","title":"Paramagnetic Organometallic Complexes","year":2005,"lang":"en","type":"other","venue":"Encyclopedia of Inorganic and Bioinorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Reactivity (psychology); Organometallic chemistry; Homoleptic; Steric effects; Group 2 organometallic chemistry; Ligand (biochemistry); Paramagnetism; Agostic interaction; Crystallography; Lanthanide; Open shell; Computational chemistry; Stereochemistry; Molecule; Metal; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001121205,0.0009648655,0.001438624,0.0001691961,0.0000957854,0.00005434296,0.0009244023,0.0008794245,0.612668],"category_scores_gemma":[0.000124453,0.0009317491,0.0003036834,0.0005095087,0.0005324236,0.00005778487,0.0005151542,0.0005353623,0.0002837518],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008866641,"about_ca_system_score_gemma":0.0002289081,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001301988,"about_ca_topic_score_gemma":0.00006181113,"domain_scores_codex":[0.9967659,0.00002097298,0.0009438258,0.001092721,0.00054174,0.0006348817],"domain_scores_gemma":[0.9973159,0.0001207264,0.0008268332,0.001325711,0.00006045307,0.0003504067],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0000340969,0.0009164487,0.001404005,0.005570032,0.001594176,0.00003783644,0.0003776188,1.936337e-7,0.8253744,0.0001171863,0.09266298,0.07191102],"study_design_scores_gemma":[0.0006433356,0.00002029688,0.0001745487,0.0003004199,0.000651436,0.00008888342,0.0003364455,0.000005849168,0.06713483,0.00003307828,0.9294575,0.001153397],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.02703997,0.01727459,0.00001360743,0.0001029667,0.00009824559,0.0001383123,0.0004641248,0.0004357469,0.9544324],"genre_scores_gemma":[0.03411775,0.01398799,0.0005168633,0.00004043329,0.001605885,0.00001772444,0.0004171403,0.0009256385,0.9483706],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.8367945,"threshold_uncertainty_score":0.9993133,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005550883904330077,"score_gpt":0.1973822195196456,"score_spread":0.1918313356153155,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}