{"id":"W4205674347","doi":"10.26434/chemrxiv-2022-s0p9c","title":"Dynamics of small molecules within the F127 PEO-PPO-PEO triblock copolymer gel and sol phases studied at the molecular scale","year":2022,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Micelle; Excited state; Reaction rate constant; Photochemistry; Quenching (fluorescence); Chemistry; Flash photolysis; Aqueous solution; Fluorescence; Physical chemistry; Kinetics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000736442,0.0001730501,0.000131219,0.0001040443,0.0001183435,0.0001783063,0.0001140907,0.00013904,0.001021829],"category_scores_gemma":[0.0001551431,0.00006719597,0.0001037719,0.0000915612,0.0002043485,0.00032008,0.00009164016,0.0003808177,0.0002113821],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002435127,"about_ca_system_score_gemma":0.0001562433,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006586626,"about_ca_topic_score_gemma":0.0004324709,"domain_scores_codex":[0.9999629,0.000003582989,0.000001253068,0.00001084208,0.00001168852,0.00000960298],"domain_scores_gemma":[0.9999137,0.00003125576,0.00002566661,0.000003664511,0.0000125031,0.00001325698],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.00005027095,0.00001170199,0.0002019848,0.00002228969,0.000003336594,0.00003002708,0.00004309155,0.0002697424,0.9981778,0.0001445918,0.00001513198,0.001030134],"study_design_scores_gemma":[0.000005349098,0.0001721289,0.00276048,0.000005815746,0.000008499509,0.00005168452,0.00003566496,0.003866274,0.9921136,0.00009357109,0.0008800466,0.000006983915],"study_design_candidate":"simulation_or_modeling","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971811,0.000290942,0.001729351,0.00002321076,0.000004218568,0.00001044655,0.00009292514,0.00002894703,0.0006389341],"genre_scores_gemma":[0.9957749,0.0003830757,0.001834959,0.00001856771,0.000004169962,0.00002699082,0.0002064669,0.00002147968,0.001729434],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001021829,"threshold_uncertainty_score":0.003418386,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01327625546783717,"score_gpt":0.2411734261678253,"score_spread":0.2278971706999881,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}