{"id":"W4205820688","doi":"10.1002/cmtd.202100101","title":"Pressurized Sample Infusion","year":2022,"lang":"en","type":"article","venue":"Chemistry - Methods","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Mass spectrometry; Ion; Cover (algebra); Electrospray ionization; Analytical Chemistry (journal); Kinetics; Sample (material); Ionization; Electrospray; Abundance (ecology); Order (exchange); Chemistry; Chromatography; Physics; Organic chemistry; Engineering; Mechanical engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007800931,0.00080504,0.0007123832,0.0006742468,0.0003477731,0.0009707808,0.000915585,0.0009007697,0.04297963],"category_scores_gemma":[0.0009291804,0.0003502484,0.0004509894,0.0004550851,0.0003750128,0.0007409133,0.0007299981,0.002324978,0.03293234],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000357537,"about_ca_system_score_gemma":0.0007253119,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005077159,"about_ca_topic_score_gemma":0.0006024658,"domain_scores_codex":[0.9993923,0.00005719302,0.00003061643,0.0001983805,0.0002571822,0.00006431721],"domain_scores_gemma":[0.999647,0.00006372122,0.00003801062,0.0000940962,0.00009958141,0.00005749408],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002033359,0.0004181101,0.0005348743,0.001047874,0.00007711454,0.0006510509,0.0001109827,0.000269653,0.7096907,0.003320874,0.05940555,0.2224398],"study_design_scores_gemma":[0.0002910724,0.001690874,0.003408674,0.0002133585,0.00007217269,0.001583093,0.00004448789,0.001379697,0.4432331,0.001133069,0.5468735,0.00007688285],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.123527,0.08255342,0.5346482,0.004723415,0.02080888,0.0134071,0.0284704,0.03908487,0.1527767],"genre_scores_gemma":[0.2611802,0.04865269,0.2730595,0.01074416,0.004046691,0.01132663,0.03142023,0.005213675,0.3543561],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.04297963,"threshold_uncertainty_score":0.1437812,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02650716082012265,"score_gpt":0.3554069682077208,"score_spread":0.3288998073875982,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}