{"id":"W4205820688","doi":"10.1002/cmtd.202100101","title":"Pressurized Sample Infusion","year":2022,"lang":"en","type":"article","venue":"Chemistry - Methods","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Mass spectrometry; Ion; Cover (algebra); Electrospray ionization; Analytical Chemistry (journal); Kinetics; Sample (material); Ionization; Electrospray; Abundance (ecology); Order (exchange); Chemistry; Chromatography; Physics; Organic chemistry; Engineering; Mechanical engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004714341,0.0001604949,0.0002049114,0.00002189543,0.000372335,0.00003111423,0.0005167166,0.00008311178,0.1313728],"category_scores_gemma":[0.0002339569,0.0001790197,0.000122886,0.0002972682,0.00004390496,0.00003271414,0.000527653,0.0004526422,0.000003850229],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001288479,"about_ca_system_score_gemma":0.00004494435,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003233093,"about_ca_topic_score_gemma":9.473345e-8,"domain_scores_codex":[0.9988476,0.00004848064,0.0002188597,0.0003875851,0.0002344499,0.0002629951],"domain_scores_gemma":[0.9986678,0.0003212839,0.0001345638,0.0007391353,0.00003418618,0.0001030753],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001447305,0.00009214271,0.0001555562,0.000086064,0.00001575745,0.000001890024,0.00003431621,0.00001104926,0.9803382,0.0006589259,0.003321617,0.01527003],"study_design_scores_gemma":[0.0001398177,0.000003894534,0.000006439878,0.000002599986,0.00001315844,0.00001332784,0.00005768863,0.0004320974,0.5496025,0.005485791,0.444114,0.0001286773],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"methods","genre_scores_codex":[0.1323826,0.0007738254,0.07977554,0.0009922654,0.0001173016,0.0002649544,0.0005387076,0.001748035,0.7834068],"genre_scores_gemma":[0.2472485,0.00004985579,0.7231548,0.00015173,0.0002835946,0.001211951,0.000431557,0.00007106586,0.02739695],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.7560098,"threshold_uncertainty_score":0.8694213,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02650716082012265,"score_gpt":0.3554069682077208,"score_spread":0.3288998073875982,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}