{"id":"W4206079113","doi":"10.1039/d1cp05130j","title":"Surface sensitive infrared spectroelectrochemistry using palladium electrodeposited on ITO-modified internal reflection elements","year":2022,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Palladium; Attenuated total reflection; Infrared spectroscopy; Materials science; Infrared; Oxide; Analytical Chemistry (journal); Chemistry; Optics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001589821,0.0004641615,0.0002996592,0.0003025105,0.0001843281,0.0002697532,0.000700591,0.0003162716,0.001465388],"category_scores_gemma":[0.0003166968,0.0002546893,0.0002768401,0.0003949337,0.0002481795,0.0001988736,0.0001903396,0.0007820078,0.0004739697],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000334126,"about_ca_system_score_gemma":0.0001608305,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000785414,"about_ca_topic_score_gemma":0.001233616,"domain_scores_codex":[0.9997713,0.00002674078,0.000009114941,0.00008388646,0.00008528488,0.00002364541],"domain_scores_gemma":[0.9998436,0.00006278091,0.00003387357,0.00001908675,0.00002984183,0.0000108476],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002614823,0.00001098611,0.0002081128,0.00004412975,0.000007473283,0.00003904102,0.00002299059,0.0001010138,0.9976761,0.0001340443,0.00004364142,0.001686373],"study_design_scores_gemma":[0.000002320941,0.00005904122,0.001133136,0.000002934596,0.000009158758,0.00009179662,0.00001670576,0.002056586,0.996233,0.00003842677,0.0003540547,0.000002805846],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9452803,0.0007955377,0.04663911,0.00008261534,0.00005981226,0.00003613488,0.0005291803,0.0009913155,0.005586005],"genre_scores_gemma":[0.9629418,0.000979237,0.03181394,0.00005824784,0.000008773332,0.0000407652,0.0006242692,0.00009655587,0.003436558],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001465388,"threshold_uncertainty_score":0.004902184,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01550732396620401,"score_gpt":0.2696133348605115,"score_spread":0.2541060108943075,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}