{"id":"W4206086712","doi":"10.1002/ange.201906755","title":"Mechanochemistry for Synthesis","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":284,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Mechanochemistry; Ball mill; Grinding; Covalent bond; Molecule; Nanotechnology; Chemistry; Materials science; Organic chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00004232918,0.0001323835,0.0001435016,0.00002558108,0.00005275371,0.00002566368,0.0001551336,0.0001251041,0.003616672],"category_scores_gemma":[0.0000765657,0.0001358764,0.0002396771,0.0000621209,0.00001966779,0.00005163173,0.0000302474,0.0000985999,0.00003874844],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003051376,"about_ca_system_score_gemma":0.00002199349,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008313999,"about_ca_topic_score_gemma":0.00000261733,"domain_scores_codex":[0.9992924,0.000001656754,0.000128754,0.0002624088,0.00009599062,0.0002187717],"domain_scores_gemma":[0.9993468,0.0001357815,0.0000542868,0.0003434796,0.00005349692,0.00006616962],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003239796,0.00004190531,0.0001217431,0.0001769911,0.0000714819,0.000001933993,0.00002844497,0.000001379929,0.9956239,0.0001370314,0.0034202,0.0003425373],"study_design_scores_gemma":[0.0002188192,0.00000509339,0.000002645603,0.00004599772,0.00003959838,0.00001038971,0.0001467356,0.000006926773,0.8559548,0.0002501218,0.1431691,0.0001497949],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7424682,0.0002661002,0.0003636805,0.0002310477,0.0001879549,0.0001316718,0.0002097103,0.0001876772,0.2559539],"genre_scores_gemma":[0.9908875,0.0000197886,0.0004873035,0.0001051415,0.0001292734,0.0001608447,0.00009166908,0.00002746034,0.008091051],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2484192,"threshold_uncertainty_score":0.9972941,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01075630370983611,"score_gpt":0.2362235273607528,"score_spread":0.2254672236509167,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}