{"id":"W4206125124","doi":"10.1016/b978-0-12-820206-7.00077-9","title":"Cyclic and Non-Cyclic Pi Complexes of Manganese","year":2021,"lang":"en","type":"book-chapter","venue":"Elsevier eBooks","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"","keywords":"Allene; Chemistry; Heteroatom; Cyclopentadienyl complex; Alkene; Propargyl; Manganese; Alkyne; Ketene; Reactivity (psychology); Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis; Ring (chemistry)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005283007,0.0003166907,0.000114505,0.0001759928,0.0002028198,0.0004687821,0.0005038322,0.0001806401,0.01643376],"category_scores_gemma":[0.00008754882,0.0001506721,0.00008663842,0.0002985627,0.0002132713,0.000614655,0.0003099178,0.0003493855,0.001755454],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005338368,"about_ca_system_score_gemma":0.0001863229,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006645226,"about_ca_topic_score_gemma":0.001353396,"domain_scores_codex":[0.9999696,0.000002005337,0.000001409665,0.000008667514,0.00001303093,0.000005340985],"domain_scores_gemma":[0.9999862,0.00000441983,0.000002063181,0.000002828117,0.00000208284,0.000002519232],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003703442,0.0001135135,0.000194403,0.00159945,0.00001571272,0.0004136225,0.0002644536,0.001870382,0.4279577,0.1820221,0.03358923,0.3515892],"study_design_scores_gemma":[0.00002013133,0.0002381342,0.0008633821,0.00008917464,0.00001482802,0.0009279976,0.00008063998,0.001437667,0.1784488,0.02478746,0.7930745,0.00001729443],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.11793,0.05152621,0.01643772,0.0008041621,0.001314037,0.00007707439,0.0005503635,0.0004924223,0.810868],"genre_scores_gemma":[0.2372369,0.0205384,0.004937274,0.0002665215,0.0001542088,0.00005161704,0.0005936495,0.0001310177,0.7360904],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01643376,"threshold_uncertainty_score":0.05497634,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01334392634478051,"score_gpt":0.2196924237962307,"score_spread":0.2063484974514501,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}