{"id":"W4206476185","doi":"10.1039/d1sc05692a","title":"Multi-resonant thermally activated delayed fluorescence emitters based on tetracoordinate boron-containing PAHs: colour tuning based on the nature of chelates","year":2022,"lang":"en","type":"article","venue":"Chemical Science","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Henan Agricultural University; Beijing Institute of Technology; Natural Science Foundation of Heilongjiang Province; Tsinghua University; Fonds De La Recherche Scientifique - FNRS; National Natural Science Foundation of China; Waalse Gewest; Fédération Wallonie-Bruxelles; Engineering and Physical Sciences Research Council; Leverhulme Trust","keywords":"Tetracoordinate; Chelation; Fluorescence; Boron; Photochemistry; Molecule; Ligand (biochemistry); Quantum efficiency; Chemistry; Covalent bond; Intersystem crossing; OLED; Absorption (acoustics); Materials science; Inorganic chemistry; Organic chemistry; Excited state; Optoelectronics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003510579,0.0003927606,0.0004013846,0.0002747854,0.0001734604,0.0004068288,0.0005720426,0.0005026945,0.001047482],"category_scores_gemma":[0.0003004361,0.0002230094,0.0002491698,0.0002152776,0.0003574612,0.0007650093,0.0004258081,0.0006192462,0.0004718317],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003116077,"about_ca_system_score_gemma":0.0001532517,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002553254,"about_ca_topic_score_gemma":0.0004762691,"domain_scores_codex":[0.9998428,0.00001866581,0.0000109496,0.00005175039,0.00003357393,0.00004222213],"domain_scores_gemma":[0.9998441,0.0000353351,0.00004303019,0.00001959447,0.0000289333,0.00002892282],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005248054,0.000009547396,0.00005781753,0.00004893241,0.00000360422,0.00002856798,0.00002291783,0.00007871084,0.9971909,0.0004760905,0.00003956286,0.00199103],"study_design_scores_gemma":[0.000006396204,0.00005513102,0.0001342382,0.000002122054,0.000005228875,0.0000843489,0.000006078787,0.0005656607,0.998018,0.00004262369,0.001072689,0.000007418276],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9325049,0.002709041,0.05899038,0.0002057652,0.00006338864,0.00006699703,0.000298015,0.0005672676,0.004594247],"genre_scores_gemma":[0.9572136,0.001375125,0.03807797,0.00007199089,0.0000158034,0.00004866314,0.0001707179,0.00006135766,0.002964939],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001047482,"threshold_uncertainty_score":0.003504217,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01026295294925636,"score_gpt":0.2405655699387321,"score_spread":0.2303026169894758,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}