{"id":"W4206766369","doi":"10.1016/j.cattod.2022.01.001","title":"Experimental study on the role of water and kinetic enhancement in the one-step synthesis of methyl isobutyl ketone via catalytic distillation","year":2022,"lang":"en","type":"article","venue":"Catalysis Today","topic":"Process Optimization and Integration","field":"Engineering","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Waterloo; Datec Coating (Canada)","funders":"Natural Sciences and Engineering Research Council of Canada; University of Waterloo; Ministry of Training, Colleges and Universities","keywords":"Methyl isobutyl ketone; Chemistry; Catalysis; Acetone; Reboiler; Distillation; Yield (engineering); Chemical engineering; Ketone; Chromatography; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003149583,0.00008715017,0.0001497415,0.00009194534,0.00006031756,0.00001094372,0.000142827,0.00001415017,0.0001371687],"category_scores_gemma":[0.00002429114,0.00005176576,0.00003178247,0.0001967014,0.00002557263,0.00005306395,0.00004085514,0.00007316275,0.00000239536],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005278549,"about_ca_system_score_gemma":0.000003591993,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005903959,"about_ca_topic_score_gemma":0.00001131878,"domain_scores_codex":[0.9992454,0.00008256,0.0002469433,0.0001136153,0.0002301599,0.00008130218],"domain_scores_gemma":[0.9996159,0.00008664261,0.00004556152,0.0002206057,0.00002008628,0.00001119084],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007316705,0.001552914,0.001051799,0.00005230916,0.0002587416,8.954857e-7,0.04521988,0.07649679,0.8669959,0.0003997589,0.00006180884,0.007835985],"study_design_scores_gemma":[0.0001302744,0.0001206572,0.0006447572,0.000007243495,0.00005602573,4.159706e-7,0.009641718,0.05719863,0.932008,0.00002087821,0.0001028773,0.00006857373],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969428,0.0003405241,0.001232335,0.00008022288,0.0000269125,0.0003337873,0.000008692121,0.00001156085,0.001023143],"genre_scores_gemma":[0.999617,0.000008653251,0.00002840939,0.00001669327,0.00000609904,0.0002443944,0.00004938005,0.000009513064,0.00001985383],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.065012,"threshold_uncertainty_score":0.2110946,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01000155680042495,"score_gpt":0.223389356192887,"score_spread":0.213387799392462,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}