{"id":"W4206773655","doi":"10.1002/0470845805.ch9","title":"Carbocations","year":2001,"lang":"en","type":"other","venue":"Organic Reaction Mechanisms/Organic reaction mechanisms","topic":"Catalysis and Hydrodesulfurization Studies","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Carbocation; Chemistry; Oxonium ion; Allylic rearrangement; Heteroatom; Ion; Photochemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","insufficient_payload"],"category_scores_codex":[0.0004359845,0.001345968,0.001334468,0.001479904,0.0004213099,0.0002097092,0.000596442,0.001396248,0.01580587],"category_scores_gemma":[0.00009715275,0.001495817,0.0004281949,0.001928896,0.00006201206,0.000396766,0.0001481129,0.001061187,0.005235138],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001004512,"about_ca_system_score_gemma":0.0001461656,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002594783,"about_ca_topic_score_gemma":0.0008456262,"domain_scores_codex":[0.9953002,0.000113839,0.001180206,0.001325746,0.001134353,0.000945666],"domain_scores_gemma":[0.9969172,0.00007094658,0.0007194782,0.001672351,0.0002207575,0.0003992969],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00000548439,0.0001089854,7.000487e-7,0.0001186497,0.0006591449,0.00002078257,0.0001218273,0.00002194207,0.8692141,0.007626331,0.1207589,0.001343137],"study_design_scores_gemma":[0.001372585,0.0001458537,0.000029786,0.0003346257,0.001319224,0.0006026582,0.001705974,0.0009560505,0.2477806,0.008940967,0.7339264,0.002885242],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"methods","genre_gemma":"other","genre_scores_codex":[0.0001574958,0.0008999557,0.6769745,0.0002996119,0.009613466,0.001532376,0.0001868514,0.008946184,0.3013896],"genre_scores_gemma":[0.04958931,0.02112321,0.006712421,0.0004504903,0.003103126,0.0004512734,0.002229574,0.006625346,0.9097152],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.6702621,"threshold_uncertainty_score":0.9999291,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008814417520300093,"score_gpt":0.2079410455396793,"score_spread":0.1991266280193792,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}