{"id":"W4207000782","doi":"10.1002/ange.202110575","title":"Divergent and Modular Synthesis of Terpenoid Scaffolds via a Au<sup>I</sup> Catalyzed One‐Pot Cascade","year":2021,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Transport Canada; OmegaChem (Canada); University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Steric effects; Stereoselectivity; Chemistry; Combinatorial chemistry; Cascade; Lewis acids and bases; Catalysis; Divergent synthesis; Ligand (biochemistry); Cascade reaction; Stereochemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001684124,0.0006179431,0.0002800256,0.0002229182,0.0001944796,0.0003457242,0.0004443603,0.0002468828,0.002483681],"category_scores_gemma":[0.0001754929,0.0001668937,0.0002550857,0.0002298784,0.0003543184,0.0004939745,0.0004800805,0.0008480291,0.001243659],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002824062,"about_ca_system_score_gemma":0.0003361343,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003122429,"about_ca_topic_score_gemma":0.0008753417,"domain_scores_codex":[0.9998463,0.00001302389,0.00001059464,0.00005255189,0.00002890711,0.00004854474],"domain_scores_gemma":[0.9999003,0.00001687929,0.00002339654,0.00001871015,0.00001428018,0.0000264352],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009401719,0.00006566745,0.00008973083,0.0001275783,0.00001435994,0.0003860712,0.00009523372,0.001023907,0.9743685,0.003683893,0.0004536647,0.0195974],"study_design_scores_gemma":[0.00002094077,0.0002503023,0.0002356423,0.000005585475,0.00001103986,0.0001949947,0.00001296781,0.001001886,0.9914666,0.0003532946,0.00643417,0.00001256726],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7419519,0.002794613,0.1948488,0.0005979917,0.0004322711,0.0006082417,0.001351621,0.00192094,0.05549358],"genre_scores_gemma":[0.9304815,0.001425303,0.05814449,0.00013716,0.00003274287,0.0001493866,0.0003181605,0.0001146044,0.009196611],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002483681,"threshold_uncertainty_score":0.008308768,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01451313299504485,"score_gpt":0.2244623917332887,"score_spread":0.2099492587382439,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}