{"id":"W4207002566","doi":"10.1021/acscatal.1c04983","title":"Polycationic Rh–JosiPhos Polymers Supported on Phosphotungstic Acid/Al<sub>2</sub>O<sub>3</sub> by Multiple Electrostatic Attractions","year":2022,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"ROMP; Phosphotungstic acid; Cationic polymerization; Norbornene; Monomer; Chemistry; Polymer chemistry; Polymer; Metathesis; Cyclooctene; Catalysis; Ring-opening metathesis polymerisation; Copolymer; Olefin fiber; Organic chemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003823138,0.0006397911,0.0006861471,0.0007968229,0.001363222,0.0001455571,0.000785332,0.0002128286,0.001753233],"category_scores_gemma":[0.0005163118,0.0007594996,0.0006260308,0.004114251,0.0001481221,0.0003562863,0.0002297282,0.0009496625,0.0006871749],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00121143,"about_ca_system_score_gemma":0.0003693165,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002898484,"about_ca_topic_score_gemma":0.0001082209,"domain_scores_codex":[0.9951582,0.0001165887,0.0009911851,0.001236945,0.001483462,0.00101362],"domain_scores_gemma":[0.9967397,0.0004977605,0.0007085126,0.001422146,0.0001800349,0.0004518898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001130688,0.0007902681,0.0007778306,0.00003023978,0.0009473534,0.0000276211,0.0003834253,0.000244585,0.9589067,0.00002072905,0.01366301,0.02409514],"study_design_scores_gemma":[0.001181222,0.00007878801,0.0003733625,0.00001000511,0.001016686,0.00005011594,0.001064016,0.001980613,0.9867836,0.00002354545,0.006642199,0.0007958813],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941252,0.001149533,0.0004361994,0.001182712,0.0001902083,0.0002778575,0.00103684,0.0004061614,0.00119531],"genre_scores_gemma":[0.9828572,0.0003335798,0.00001982337,0.001464529,0.00006543416,0.0006986548,0.01359149,0.0001522964,0.000817008],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02787684,"threshold_uncertainty_score":0.9999369,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006485056221574027,"score_gpt":0.2132445157956943,"score_spread":0.2067594595741203,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}