{"id":"W4207069523","doi":"10.1016/j.ceja.2022.100250","title":"Innovative cycling reaction mechanisms of CO2 absorption in amino acid salt solvents","year":2022,"lang":"en","type":"article","venue":"Chemical Engineering Journal Advances","topic":"Carbon Dioxide Capture Technologies","field":"Engineering","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba; Children's Hospital Research Institute of Manitoba","funders":"National Institute of Food and Agriculture; U.S. Department of Agriculture; U.S. Department of Energy","keywords":"Chemistry; Deprotonation; Bicarbonate; Zwitterion; Base (topology); Absorption (acoustics); Salt (chemistry); Carbamate; Inorganic chemistry; Protonation; Organic base; Solvent; Carbonation; Organic chemistry; Nuclear chemistry; Materials science; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002002713,0.000157038,0.0002506633,0.0003198142,0.00001771709,0.00001036867,0.0002123706,0.00006951766,0.00001413435],"category_scores_gemma":[0.0001646803,0.000173146,0.00005771023,0.0006766502,0.00002078993,0.000238186,0.00007413304,0.0008718213,8.729859e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003916855,"about_ca_system_score_gemma":0.00001038768,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000102179,"about_ca_topic_score_gemma":2.337358e-7,"domain_scores_codex":[0.9989444,0.000007201008,0.0004159512,0.0001307075,0.0002637427,0.0002380118],"domain_scores_gemma":[0.9996408,0.00005043839,0.0001059672,0.0001162041,0.00004858418,0.00003796127],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001054657,0.00001400179,0.0000237252,0.0000446027,0.00001442499,0.000009067919,0.0000558331,0.2119504,0.7854201,0.0004422752,0.00001306076,0.002002055],"study_design_scores_gemma":[0.0003309239,0.00003503222,0.0001265453,0.00008062698,0.000005779666,0.0000965599,0.0002217737,0.01667407,0.9790855,0.002704261,0.0004510834,0.0001878475],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9473972,0.001584426,0.04973987,0.00003380706,0.0007032822,0.00008643023,0.000006503437,0.000350072,0.00009839932],"genre_scores_gemma":[0.9926312,0.0001511981,0.007088739,0.000007760224,0.00005269884,0.00002765097,0.000005784023,0.00003196964,0.000003011935],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1952763,"threshold_uncertainty_score":0.7060688,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006443049173884549,"score_gpt":0.2072250640407347,"score_spread":0.2007820148668502,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}