{"id":"W4210681840","doi":"10.1002/ange.201802090","title":"Nickel Fluorocarbene Metathesis with Fluoroalkenes","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Directorate for Mathematical and Physical Sciences; Welch Foundation","keywords":"Metathesis; Carbene; Alkene; Chemistry; Nickel; Trifluoromethyl; Salt metathesis reaction; Yield (engineering); Medicinal chemistry; Organic chemistry; Catalysis; Polymerization; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001036956,0.0003164822,0.0001614813,0.0002006549,0.0001823482,0.0002362489,0.0002547246,0.0003141503,0.00279881],"category_scores_gemma":[0.0002127966,0.0001334037,0.0001975079,0.0001415137,0.0001337678,0.0003188696,0.0002764601,0.0003834241,0.0006757968],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004097643,"about_ca_system_score_gemma":0.0002163204,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004584593,"about_ca_topic_score_gemma":0.0009891202,"domain_scores_codex":[0.9998847,0.00001509521,0.000007207419,0.00002212863,0.00003069386,0.00004014876],"domain_scores_gemma":[0.9999588,0.000007890128,0.000008088684,0.00001175223,0.000005318665,0.000008126733],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001636055,0.00004447973,0.0002427884,0.0001612813,0.00001923411,0.0004192216,0.0001157511,0.001078303,0.9817515,0.004726217,0.0003954985,0.01088221],"study_design_scores_gemma":[0.00001012328,0.0001361573,0.0003536653,0.000006475809,0.000006443418,0.0001486303,0.00001298748,0.0008360248,0.9933648,0.0001939831,0.004924993,0.000005882732],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.954179,0.001753671,0.009765412,0.0002245716,0.00009793941,0.00007314701,0.0002837038,0.0003245416,0.03329793],"genre_scores_gemma":[0.9945331,0.0004314714,0.001997948,0.0000222562,0.000006330875,0.00001368775,0.00008278405,0.00002255709,0.002889937],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00279881,"threshold_uncertainty_score":0.009362876,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01976845802395993,"score_gpt":0.2587027952258495,"score_spread":0.2389343372018896,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}