{"id":"W4210681840","doi":"10.1002/ange.201802090","title":"Nickel Fluorocarbene Metathesis with Fluoroalkenes","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Directorate for Mathematical and Physical Sciences; Welch Foundation","keywords":"Metathesis; Carbene; Alkene; Chemistry; Nickel; Trifluoromethyl; Salt metathesis reaction; Yield (engineering); Medicinal chemistry; Organic chemistry; Catalysis; Polymerization; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002428894,0.000388472,0.0004160012,0.00003414421,0.0001512085,0.00005471204,0.0004954989,0.0002226735,0.009136988],"category_scores_gemma":[0.0002241617,0.0003205293,0.0001303535,0.0002613316,0.0003967356,0.0001070328,0.0001273011,0.000201747,0.0002100451],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001079798,"about_ca_system_score_gemma":0.0001080204,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004538463,"about_ca_topic_score_gemma":0.00001358244,"domain_scores_codex":[0.9980981,0.00001628296,0.0003051022,0.0006399743,0.0004008566,0.0005396374],"domain_scores_gemma":[0.9982426,0.0002159107,0.0001440681,0.001024738,0.0001485876,0.000224146],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000710287,0.00006960468,0.0005262303,0.00008627021,0.000157679,0.00001925535,0.0003128629,1.054489e-7,0.9919453,0.0000216399,0.001439737,0.005350285],"study_design_scores_gemma":[0.0006244834,0.0000337778,0.00003560393,0.00007939662,0.0001765018,0.0001263164,0.0003972159,0.00000631613,0.9664199,0.0001822199,0.03148,0.0004382506],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7439165,0.0008685086,0.0002880866,0.0003874961,0.0001023825,0.00006348902,0.00003106702,0.000414254,0.2539282],"genre_scores_gemma":[0.9601903,0.00005861734,0.02293701,0.0001804121,0.001265107,0.00004739993,0.00003062691,0.0001279395,0.01516259],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2387657,"threshold_uncertainty_score":0.9999247,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01976845802395993,"score_gpt":0.2587027952258495,"score_spread":0.2389343372018896,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}