{"id":"W4210691984","doi":"10.1016/j.ijbiomac.2022.01.182","title":"Determination of CO2 solubility in semi-crystalline polylactic acid with consideration of rigid amorphous fraction","year":2022,"lang":"en","type":"article","venue":"International Journal of Biological Macromolecules","topic":"Polymer Foaming and Composites","field":"Materials Science","cited_by":17,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Solubility; Amorphous solid; Phase (matter); Gravimetric analysis; Sorption; Polymer; Polylactic acid; Tacticity; Materials science; Hildebrand solubility parameter; Chemical engineering; Thermodynamics; Chemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002611106,0.000421122,0.0002060394,0.0003442554,0.0003560846,0.0003410246,0.0001985729,0.0003254842,0.0004930078],"category_scores_gemma":[0.0003758547,0.0001808204,0.0002169938,0.0004542469,0.0004054381,0.000426786,0.0002034671,0.0004334331,0.0001866239],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002751429,"about_ca_system_score_gemma":0.0003413156,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002636327,"about_ca_topic_score_gemma":0.003532278,"domain_scores_codex":[0.9998012,0.00004338266,0.0000166802,0.000048869,0.00005364057,0.00003626735],"domain_scores_gemma":[0.9996724,0.0001481791,0.00005170512,0.00003193658,0.0000691238,0.00002668574],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000139202,0.00001333315,0.0005124756,0.00002324894,0.000004697296,0.00004561853,0.00003750656,0.0002004784,0.9981846,0.00006653541,0.000008066874,0.000764175],"study_design_scores_gemma":[0.000001305962,0.00004377909,0.001291772,0.000001511301,0.000004569144,0.00002174989,0.00001747797,0.001197593,0.9972153,0.00001609878,0.0001861796,0.0000026133],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.992591,0.0008408699,0.004819784,0.00002663613,0.000009291059,0.00001742034,0.0001834648,0.00003914484,0.001472211],"genre_scores_gemma":[0.9963671,0.0002959478,0.002297255,0.00000833482,0.000004270265,0.00002163243,0.0002226251,0.00002024783,0.0007626697],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002636327,"threshold_uncertainty_score":0.00524193,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01560401705413125,"score_gpt":0.2635123108545225,"score_spread":0.2479082938003912,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}