{"id":"W4210952328","doi":"10.1002/ange.202011372","title":"Reversible Silylium Transfer between P‐H and Si‐H Donors","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; Max-Planck-Gesellschaft","keywords":"Silane; Chemistry; Silanes; Electrophile; Adduct; Phosphine; Lewis acids and bases; Hydrosilylation; Catalysis; Medicinal chemistry; Polymer chemistry; Ligand (biochemistry); Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008763836,0.0002285176,0.0001176781,0.00009224046,0.0001342917,0.0001888257,0.0003075662,0.0001469464,0.003455006],"category_scores_gemma":[0.0001207188,0.0001239975,0.00007879564,0.00006901974,0.0002043212,0.0002901492,0.0003875705,0.0002782267,0.0004457091],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001919217,"about_ca_system_score_gemma":0.0001188375,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002019031,"about_ca_topic_score_gemma":0.0003347075,"domain_scores_codex":[0.9999419,0.000007924003,0.000002147448,0.00001220366,0.00001299786,0.00002277635],"domain_scores_gemma":[0.9999557,0.00001419332,0.000008863157,0.000007260023,0.000003714435,0.00001036152],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001696817,0.00002983307,0.0002024319,0.0001103321,0.00001043502,0.0001954008,0.00008888376,0.000314214,0.9918464,0.00211429,0.0002010299,0.004717218],"study_design_scores_gemma":[0.00001630935,0.0001126154,0.0002453308,0.000001965377,0.000003286811,0.00006016214,0.00001519536,0.0008995236,0.9969524,0.0001355517,0.001554331,0.000003198255],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9921515,0.0002342328,0.002350765,0.00004316353,0.00001926692,0.00001869171,0.00004626463,0.0001108752,0.005025195],"genre_scores_gemma":[0.9978653,0.00007915193,0.0004117283,0.00001106264,0.000003377904,0.000005939855,0.0000265118,0.000009018738,0.001588089],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003455006,"threshold_uncertainty_score":0.01155818,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02138417982758858,"score_gpt":0.2235692850755654,"score_spread":0.2021851052479768,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}