{"id":"W4211197148","doi":"10.1002/9780470975800.ch7","title":"Carbocations","year":2007,"lang":"en","type":"other","venue":"Organic Reaction Mechanisms/Organic reaction mechanisms","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Carbocation; Chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"category_scores_codex":[0.001289457,0.002751374,0.002249959,0.002614469,0.0006938179,0.000354634,0.00177298,0.005222349,0.1179893],"category_scores_gemma":[0.0007931099,0.0031154,0.00103319,0.002558232,0.0001816176,0.0006501045,0.0005057346,0.003867273,0.01308296],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00344407,"about_ca_system_score_gemma":0.0008504253,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006198369,"about_ca_topic_score_gemma":0.0004530168,"domain_scores_codex":[0.9881043,0.0001807153,0.002465178,0.00365461,0.003238993,0.002356166],"domain_scores_gemma":[0.9903998,0.0003896736,0.003234555,0.003960215,0.0005532529,0.001462452],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007179379,0.0005183636,5.484799e-7,0.0003150734,0.0005273718,0.00009070318,0.00009324877,2.857325e-7,0.9138747,0.03448475,0.0471476,0.002875515],"study_design_scores_gemma":[0.001376899,0.0001099777,0.000002161473,0.0004467381,0.0006989942,0.0009057407,0.001002457,0.00005293121,0.652783,0.01500066,0.3254567,0.002163649],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.0003862985,0.000344112,0.2874146,0.0005057547,0.009349866,0.001544405,0.0003386241,0.00942194,0.6906944],"genre_scores_gemma":[0.01582572,0.002217324,0.01470223,0.0009234887,0.003954294,0.0003351262,0.002651107,0.007006648,0.9523841],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.2783091,"threshold_uncertainty_score":0.9985219,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0118853346241832,"score_gpt":0.2449766315323899,"score_spread":0.2330912969082067,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}