{"id":"W4212908610","doi":"10.1039/d1ja00448d","title":"GC-MS exploration of photochemically generated species of Os, W and Ru from reductive and oxidative media","year":2022,"lang":"en","type":"article","venue":"Journal of Analytical Atomic Spectrometry","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"Universidade Federal de Santa Catarina; Akademie Věd České Republiky; Grantová Agentura České Republiky; Univerzita Karlova v Praze","keywords":"Chemistry; Oxidative phosphorylation; Oxidative addition; Ruthenium; Radiochemistry; Organic chemistry; Biochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001366014,0.0006834034,0.0002319658,0.001306762,0.0005210824,0.0003017017,0.000426113,0.0005994659,0.005359045],"category_scores_gemma":[0.0003271695,0.0001605584,0.0002851251,0.0005317235,0.0003179674,0.0003559729,0.00028458,0.0005231627,0.0009176444],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003164158,"about_ca_system_score_gemma":0.0003142204,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002633899,"about_ca_topic_score_gemma":0.004780181,"domain_scores_codex":[0.999823,0.000008028177,0.000006190042,0.0000604146,0.00006613317,0.00003623091],"domain_scores_gemma":[0.9998584,0.00005898505,0.0000194554,0.000007168239,0.00003907816,0.00001694585],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001875579,0.00002668972,0.0008113087,0.0001213125,0.00001906159,0.0001774215,0.00009771861,0.0001275772,0.989622,0.0002239542,0.0001953186,0.008389989],"study_design_scores_gemma":[0.000005624373,0.0001452714,0.004690578,0.00002243042,0.00002629526,0.0003675832,0.0001483869,0.001069183,0.9888936,0.0001765477,0.004438589,0.00001595629],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9573812,0.001917119,0.01896863,0.0002028379,0.0001198318,0.0001655257,0.007107636,0.0008404542,0.01329671],"genre_scores_gemma":[0.9709773,0.001665755,0.01192595,0.0002057779,0.00003435609,0.000131043,0.00232978,0.0001605892,0.01256942],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005359045,"threshold_uncertainty_score":0.01792783,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02242887384494284,"score_gpt":0.2571681214655135,"score_spread":0.2347392476205707,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}