{"id":"W4213423738","doi":"10.26434/chemrxiv-2022-33s1j","title":"Synthesis, Structure and Thermal Properties of Volatile Group 11 Triazenides as Potential Precursors for Vapor Deposition","year":2022,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"Knut och Alice Wallenbergs Stiftelse; Vetenskapsrådet; Stiftelsen för Strategisk Forskning","keywords":"Dimer; Chemistry; Thermogravimetric analysis; Crystallography; Sublimation (psychology); Denticity; Density functional theory; Tetramer; Chemical vapor deposition; Metal; Crystal structure; Analytical Chemistry (journal); Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006602739,0.000173832,0.0001104181,0.000164332,0.000134983,0.0002019553,0.0001911911,0.0001530792,0.001146331],"category_scores_gemma":[0.000140451,0.0001545074,0.0001335693,0.0001755523,0.0001263077,0.000124399,0.000098442,0.000291772,0.0003079168],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002346346,"about_ca_system_score_gemma":0.0001091141,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005882204,"about_ca_topic_score_gemma":0.0009905923,"domain_scores_codex":[0.9999446,0.000005533042,0.000004166216,0.0000115597,0.00002281972,0.000011394],"domain_scores_gemma":[0.9999412,0.00000836735,0.0000185889,0.000008299029,0.00001731791,0.000006201836],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000254035,0.000007275719,0.000157294,0.00007837921,0.000003619182,0.00005207913,0.00003369215,0.0002150059,0.9973019,0.0001616158,0.00009610001,0.001867503],"study_design_scores_gemma":[0.000002207478,0.0001005332,0.0007545842,0.000003359594,0.000003925022,0.00006239739,0.00001980119,0.0007051221,0.9968433,0.00002270753,0.001479218,0.000002876816],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938536,0.001445748,0.001542542,0.00005145806,0.00001680456,0.00001899257,0.0003177948,0.0001001189,0.002652879],"genre_scores_gemma":[0.9935462,0.00104281,0.002176388,0.00001703522,0.000005860627,0.00002210188,0.0003484495,0.00004314436,0.002798134],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001146331,"threshold_uncertainty_score":0.003834903,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007723182866543026,"score_gpt":0.191431494327724,"score_spread":0.183708311461181,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}