{"id":"W4214543879","doi":"10.1039/d2ra00263a","title":"CO<sub>2</sub>-Assisted asymmetric hydrogenation of prochiral allylamines","year":2022,"lang":"en","type":"article","venue":"RSC Advances","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemoselectivity; Amine gas treating; Chemistry; Base (topology); Enantiomer; Solvent; Catalysis; Asymmetric hydrogenation; Enantiomeric excess; Organic chemistry; Supercritical carbon dioxide; Carbon dioxide; Combinatorial chemistry; Enantioselective synthesis; Mathematics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000977799,0.0004410772,0.000185079,0.0001863005,0.0001696201,0.0002425615,0.0003180526,0.0003445167,0.002780966],"category_scores_gemma":[0.0001607019,0.0001445918,0.00008715424,0.0002444345,0.0002098559,0.0004142717,0.0003526668,0.0005695992,0.001198673],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002165342,"about_ca_system_score_gemma":0.0001817065,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006376542,"about_ca_topic_score_gemma":0.00212777,"domain_scores_codex":[0.9999087,0.000009391385,0.000003922498,0.00002059079,0.00002359675,0.00003374867],"domain_scores_gemma":[0.9999363,0.0000087736,0.00002344784,0.000009547961,0.000009028006,0.00001279448],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000228347,0.00006928133,0.000297288,0.0003419608,0.00002779756,0.0002954697,0.0000457671,0.0002108106,0.9769779,0.001521278,0.001954548,0.01802938],"study_design_scores_gemma":[0.00001393784,0.0001093782,0.0008454931,0.000008370776,0.00001048518,0.0003365227,0.00001857956,0.0009872826,0.9870531,0.0001032847,0.01050721,0.000006411991],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8685656,0.01275699,0.0451398,0.0008637377,0.0008608045,0.0002068229,0.0008304674,0.001325837,0.06944998],"genre_scores_gemma":[0.9896762,0.001447457,0.004272425,0.0001563138,0.00007153129,0.0000294264,0.0001953939,0.00006717565,0.004084067],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002780966,"threshold_uncertainty_score":0.009303272,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0100351657904079,"score_gpt":0.2475537940741991,"score_spread":0.2375186282837912,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}